energy transition materials

DOE grants Houston-area energy tech co. over $5M for rare earth elements study

A company headquartered in The Woodlands has secured funding to study the recovery of rare earth elements as they pertain to the energy transition. Photo via tetratec.com

The Woodlands-based Tetra Technologies, an energy technology and services company, has picked up nearly $5.4 million in U.S. Department of Energy funding to study the recovery of rare earth elements and other critical minerals from coal byproducts in Pennsylvania.

The funding also will enable Tetra to explore converting coal byproducts, known as underclay, into clays that could be sold. In addition to the DOE funding, the company also secured about $1.3 million for a total of $6.7 million.

Publicly traded Tetra got the funding as part of a more than $17 million package aimed at designing and building facilities to produce rare earth elements, along with other critical minerals and materials, from coal resources. The Department of Energy (DOE) says these minerals and materials will go toward generating clean energy.

Rare earth elements can be derived from the country’s more than 250 billion tons of coal reserves, over 4 billion tons of waste coal, and about 2 billion tons of coal ash, according to DOE.

Clean energy fixtures like solar plants, wind farms, and electric vehicles generally require more minerals to build than their fossil-fuel-based counterparts, according to the International Energy Agency. For example, a typical electric car requires six times the mineral resources of a conventional car and an onshore wind plant requires nine times more mineral resources than a gas-fired plant.

The American Geosciences Institute says rare earth elements, a set of 17 metallic elements, also are an essential component of many tech-dependent products. These include cell phones, flat-screen TVs, and radar and sonar systems.

China is the top country for production of rare earth elements, with the U.S. far behind at No. 2.

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A View From HETI

Simon M. King, a Rice University sophomore, served as the first author on a recent study of a new process for recycling lithium-ion batteries. Photo courtesy Rice

Rice University researchers have uncovered a more energy-efficient and faster way to recycle critical minerals from used lithium-ion batteries.

Traditional methods rely on high heat, long processing times and harsh chemicals to recover a small fraction of critical materials from batteries used in everything from smartphones to electric vehicles. However, the team from Rice's Department of Materials Science and Nanoengineering developed a process that uses a water-based solution containing amino chlorides to extract more metals in less time

The team published the findings in a recent edition of the scientific journal Small.

Simon King, a sophomore studying chemical and biomolecular engineering who completed this work as a summer research fellow at the Rice Advanced Materials Institute, served as first author of the study. He worked with corresponding authors Pulickel Ajayan, the Benjamin M. and Mary Greenwood Anderson Professor of Engineering, and Sohini Bhattacharyya, a research scientist in Ajayan’s lab.

By using a hydroxylammonium chloride (HACI) solution, the team achieved roughly 65 percent extraction of key battery metals in just one minute at room temperature, according to the study. The efficiencies grew to roughly 75 percent for several metals under longer processing times.

“We were surprised by just how fast the reaction occurs, especially without the involvement of high temperatures,” King said in a news release. “Within the first minute, we’re already seeing the majority of the metal extraction take place.”

By not requiring high temperatures or long reaction times, Rice predicts the process could have a major impact on cost and the environmental impact of lithium battery recycling. Additionally, the water-based HACI solution makes waste handling easier and lowers certain environmental risks.

In addition to extracting the materials, the team went on to demonstrate that the recovered metals could be recycled and reprocessed into new battery materials.

“A big advantage of this system is that it works under relatively mild conditions,” Ajayan added in the release. “That opens the door to more sustainable and scalable recycling technologies.”

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