making moves

Houston chemist earns $12M grant to support innovative soil pollutant removal process

James Tour of Rice University has received funding to support his energy transition research. Photo via rice.edu

A Rice University chemist James Tour has secured a new $12 million cooperative agreement with the U.S. Army Engineer Research and Development Center on the team’s work to efficiently remove pollutants from soil.

The four-year agreement will support the team’s ongoing work on removing per- and polyfluoroalkyl substances (PFAS) from contaminated soil through its rapid electrothermal mineralization (REM) process, according to a statement from Rice.

Traditionally PFAS have been difficult to remove by conventional methods. However, Tour and the team of researchers have been developing this REM process, which heats contaminated soil to 1,000 C in seconds and converts it into nontoxic calcium fluoride efficiently while also preserving essential soil properties.

“This is a substantial improvement over previous methods, which often suffer from high energy and water consumption, limited efficiency and often require the soil to be removed,” Tour said in the statement.

The funding will help Tour and the team scale the innovative REM process to treat large volumes of soil. The team also plans to use the process to perform urban mining of electronic and industrial waste and further develop a “flash-within-flash” heating technology to synthesize materials in bulk, according to Rice.

“This research advances scientific understanding but also provides practical solutions to critical environmental challenges, promising a cleaner, safer world,” Christopher Griggs, a senior research physical scientist at the ERDC, said in the statement.

Also this month, Tour and his research team published a report in Nature Communications detailing another innovative heating technique that can remove purified active materials from lithium-ion battery waste, which can lead to a cleaner production of electric vehicles, according to Rice.

“With the surge in battery use, particularly in EVs, the need for developing sustainable recycling methods is pressing,” Tour said in a statement.

Similar to the REM process, this technique known as flash Joule heating (FJH) heats waste to 2,500 Kelvin within seconds, which allows for efficient purification through magnetic separation.

This research was also supported by the U.S. Army Corps of Engineers, as well as the Air Force Office of Scientific Research and Rice Academy Fellowship.

Last year, a fellow Rice research team earned a grant related to soil in the energy transition. Mark Torres, an assistant professor of Earth, environmental and planetary sciences; and Evan Ramos, a postdoctoral fellow in the Torres lab; were given a three-year grant from the Department of Energy to investigate the processes that allow soil to store roughly three times as much carbon as organic matter compared to Earth's atmosphere.

By analyzing samples from the East River Watershed, the team aims to understand if "Earth’s natural mechanisms of sequestering carbon to combat climate change," Torres said in a statement.

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This article originally ran on InnovationMap.

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A View From HETI

Vicki Hollub, president and CEO of Occidental, said the company's Stratos DAC project is on track to begin capturing CO2 later this year. Photo via 1pointfive.com

Houston-based Occidental Petroleum is gearing up to start removing CO2 from the atmosphere at its $1.3 billion direct air capture (DAC) project in the Midland-Odessa area.

Vicki Hollub, president and CEO of Occidental, said during the company’s recent second-quarter earnings call that the Stratos project — being developed by carbon capture and sequestration subsidiary 1PointFive — is on track to begin capturing CO2 later this year.

“We are immensely proud of the achievements to date and the exceptional record of safety performance as we advance towards commercial startup,” Hollub said of Stratos.

Carbon dioxide captured by Stratos will be stored underground or be used for enhanced oil recovery.

Oxy says Stratos is the world’s largest DAC facility. It’s designed to pull 500,000 metric tons of carbon dioxide from the air and either store it underground or use it for enhanced oil recovery. Enhanced oil recovery extracts oil from unproductive reservoirs.

Most of the carbon credits that’ll be generated by Stratos through 2030 have already been sold to organizations such as Airbus, AT&T, All Nippon Airways, Amazon, the Houston Astros, the Houston Texans, JPMorgan, Microsoft, Palo Alto Networks and TD Bank.

The infrastructure business of investment manager BlackRock has pumped $550 million into Stratos through a joint venture with 1PointFive.

As it gears up to kick off operations at Stratos, Occidental is also in talks with XRG, the energy investment arm of the United Arab Emirates-owned Abu Dhabi National Oil Co., to form a joint venture for the development of a DAC facility in South Texas. Occidental has been awarded up to $650 million from the U.S. Department of Energy to build the South Texas DAC hub.

The South Texas project, to be located on the storied King Ranch, will be close to industrial facilities and energy infrastructure along the Gulf Coast. Initially, the roughly 165-square-mile site is expected to capture 500,000 metric tons of carbon dioxide per year, with the potential to store up to 3 billion metric tons of CO2 per year.

“We believe that carbon capture and DAC, in particular, will be instrumental in shaping the future energy landscape,” Hollub said.

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