big win

Rice University team breaks records with new sunlight-to-hydrogen device

Rice University engineers have created a device that absorbs light, converts it into electricity, and then uses the electricity to split water molecules and generate hydrogen. Photo courtesy Gustavo Raskoksy/Rice University

A team of Rice University engineers have developed a scalable photoelectrochemical cell that converts sunlight into clean hydrogen at a record-setting pace.

The lab led by Aditya Mohite, an associate professor at Rice, published the findings in a study in Nature Communications late last month, in collaboration with the National Renewable Energy Laboratory, which is backed by the Department of Energy. In it, the team details how they created a device that absorbs light, converts it into electricity, and then uses the electricity to split water molecules and generate hydrogen.

Austin Fehr, a chemical and biomolecular engineering doctoral student at Rice and one of the study’s lead authors, says in a statement that the device "could open up the hydrogen economy and change the way humans make things from fossil fuel to solar fuel."

The device has a high solar-to-hydrogen conversion efficiency rate of 20.8 percent, which has yet to be reached with this type of technology, according to a release from Rice. In addition to its speed, this device is groundbreaking because it uses low-cost metal-halide perovskite semiconductors to power the reaction.

A photoreactor developed by Rice University’s Mohite research group and collaborators achieved a 20.8 percent solar-to-hydrogen conversion efficiency. Photo courtesy Gustavo Raskoksy/Rice University

“Using sunlight as an energy source to manufacture chemicals is one of the largest hurdles to a clean energy economy,” Fehr says in the statement. “Our goal is to build economically feasible platforms that can generate solar-derived fuels. Here, we designed a system that absorbs light and completes electrochemical water-splitting chemistry on its surface.”

To create the device the Mohite lab turned their existing solar cell into a reactor to split water into oxygen and hydrogen. However they continued running into issues with the semiconductors being "extremely unstable in water," according to Rice.

After two years of trials and errors, the team uncovered that by adding two layers of barriers to the semiconductors they were able to reach these record-breaking efficiency rates.

The team has also shown uses for their double barrier design with different semiconductors and for different reactions.

“We hope that such systems will serve as a platform for driving a wide range of electrons to fuel-forming reactions using abundant feedstocks with only sunlight as the energy input,” Mohite says in the statement.

The device joins another game-changing product shared in a Rice research study in recent weeks. Last month, a Rice University lab led by Haotian Wang, the William Marsh Rice Trustee Chair and an associate professor at Rice, shared their findings on how their simple plug-and-play device removes carbon dioxide from air capture to induce a water-and-oxygen-based electrochemical reaction.

Rice also recently opened registration for its 20th anniversary of Energy Tech Venture Day. Click here to register for the event on Sept. 21.

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A View From HETI

The process permanently stores some CO2 underground, reducing carbon emissions and carbon intensity. Photo courtesy UH

A new report from the University of Houston estimates that a method known as carbon dioxide-enhanced oil recovery (CO2-EOR) could recover roughly 137 billion barrels of U.S. oil—with Texas and the Gulf Coast poised to play a major role.

A UH Energy-produced white paper, titled “Revitalization of Mature Oil Fields: Opportunities and Challenges of CO2-EOR,” looks at how CO2-EOR could increase U.S. energy supply, reduce carbon emissions and lower the carbon intensity of oil production.

CO2-EOR injects pressurized carbon dioxide into mature oil wells to loosen and push oil trapped underground toward the production wells, allowing operators to extract oil typically left behind. The process permanently stores some CO2 underground, reducing carbon emissions and carbon intensity.

“Injected CO2 works to revitalize mature oil fields by reducing oil viscosity, improving sweep efficiency and restoring reservoir pressure, resulting in incremental oil production beyond primary and secondary recovery,” the report reads. “CO2-EOR also supports permanent carbon storage and by virtue of this will produce uniquely low-carbon intensity oil for global markets.”

Authored by Charles McConnell, executive director of UH's Center for Carbon Management in Energy, and Zhiyuan Li, a UH petroleum engineering doctoral candidate, the paper says that much of the opportunity lies right under the feet of Texas oil companies.

Texas and the Gulf Coast, including its offshore resources, have half of the nation's oil resources considered favorable for the CO2-EOR technology, the report says. According to UH, conventional U.S. oil reservoirs contain 624 billion barrels, with 434 billion barrels still underground, including about 20 billion barrels of proven reserves.

Still, the paper argues that the economics behind CO2-EOR need to be considered. The process’ success depends on a number of factors, including costs of carbon capture, field redevelopment, operations, monitoring, transportation and available tax incentives, according to UH.

Logistically, developing CO2-EOR operations out of older wells and infrastructure presents pros and cons. While using older wells can be more economical, aging infrastructure may require more frequent monitoring, inspection, repair or re-plugging, according to UH.

Ultimately, the report recommends focusing CO2-EOR development on mature oil fields with existing infrastructure, well-understood geology and reliable CO2 supplies. This approach, UH says, could help extend the productive life of existing oil fields while supporting “lower carbon intensity oil for global markets and a significant contribution to energy security.”

Read the full report here.

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