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Houston lab's breakthrough light-harvesting processes near market readiness

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The new process developed by Rice University researchers makes solar cells that are about 10 times more durable than traditional methods. Photos by Jeff Fitlow/Rice University

A groundbreaking Rice University lab has made further strides in its work to make harvesting light energy more efficient and stable.

Presented on the cover of a June issue of Science, a study from Rice engineer Aditya Mohite's lab uncovered a method to synthesize a high-efficiency perovskite solar cell, known as formamidinium lead iodide (FAPbI3), converting them into ultrastable high-quality photovoltaic films, according to a statement from Rice. Photovoltaic films convert sunlight into electricity.

The new process makes solar cells that are about 10 times more durable than traditional methods.

“Right now, we think that this is state of the art in terms of stability,” Mohite said in a statement. “Perovskite solar cells have the potential to revolutionize energy production, but achieving long-duration stability has been a significant challenge.”

The change come from "seasoning" the FAPbI3 with 2D halide perovskites crystals, which the Mohite lab also developed a breakthrough synthesis process for last year

The 2D perovskites helped make the FAPbI3 films more stable. The study showed that films with 2D perovskites deteriorated after two days of generating electricity, while those with 2D perovskites had not started to degrade after 20 days.

“FAPbI3 films templated with 2D crystals were higher quality, showing less internal disorder and exhibiting a stronger response to illumination, which translated as higher efficiency," Isaac Metcalf, a Rice materials science and nanoengineering graduate student and a lead author on the study, said in the statement.

Additionally, researchers say their findings could make developing light-harvesting technologies cheaper, and can also allow light-harvesting panels to be lighter weight and more flexible.

"Perovskites are soluble in solution, so you can take an ink of a perovskite precursor and spread it across a piece of glass, then heat it up and you have the absorber layer for a solar cell,” Metcalf said. “Since you don’t need very high temperatures ⎯ perovskite films can be processed at temperatures below 150 Celsius (302 Fahrenheit) ⎯ in theory that also means perovskite solar panels can be made on plastic or even flexible substrates, which could further reduce costs.”

Mohite adds this has major implications for the energy transition at large.

“If solar electricity doesn’t happen, none of the other processes that rely on green electrons from the grid, such as thermochemical or electrochemical processes for chemical manufacturing, will happen,” Mohite said. “Photovoltaics are absolutely critical.”

The Mohite lab's process for creating 2D perovskites of the ideal thickness and purity was published in Nature Synthesis last fall. At the time, Mohite said the crystals "hold the key to achieving commercially relevant stability for solar cells."

About a year ago, the lab also published its work on developing a scalable photoelectrochemical cell. The research broke records for its solar-to-hydrogen conversion efficiency rate.
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Woodside Energy has committed $12.5 million to a new partnership with Rice University. Photo via Instagram/WoodsideEnergy

Woodside Energy backs $12.5M clean energy accelerator for new technologies

howdy, partner

A global Australian energy company with its international operations in Houston has backed a new climatetech accelerator in partnership with Rice University.

Woodside Energy, headquartered in Australia with its global operations in Houston following its 2022 acquisition of BHP Group, has committed $12.5 million over the next five years to create the Woodside Rice Decarbonization Accelerator.

"The goal of the accelerator is to fast track the commercialization of innovative decarbonization technologies created in Rice labs," Rice University President Reginald DesRoches says to a crowd at the Ion at the initiative's announcement. "These technologies have the potential to make better batteries, transitistors, and other critical materials for energy technologies. In addition, the accelerator will work on manufacturing these high-value products from captured and converted carbon dioxide and methane."

"The Woodside Rice Decarbonization Accelerator will build on the work that Rice has been doing in advanced materials, energy, energy transition, and climate for many years. More than 20 percent of our faculty do some related work to energy and climate," he continues. "Harnessing their efforts alongside an esteemed partner like Woodside Energy is an exciting step that will undoubtedly have an impact far and wide."

Rice University announced the new climate tech initiative backed by Woodside Energy this week. Photo by Natalie Harms/InnovationMap

Woodside, which has over 800 employees based in Houston, has been a partner at the Ion since last spring. Daniel Kalms, Woodside Energy's CTO and executive vice president, explains that the new initiative falls in line with the three goals of Woodside's climate strategy, which includes keeping up with global energy demand, creating value, and conducting its business sustainably. The company has committed a total of $5 billion to new energy by 2030, Kalms says.

"We know that the world needs energy that is more affordable, sustainable, and secure to support the energy transition — and we want to provide that energy. Energy that is affordable, sustainable, and secure requires innovation and the application of new technology. That's what this is about," he says.

"Of course collaboration will be the key," Kalms continues. "By working with researchers, entrepreneurs, leading experts and parallel industries, we can combine our capability to solve collective challenges and create shared opportunities. That's why we are excited to be partnering with Rice."

The accelerator will be run by Paul Cherukuri, vice president of innovation at Rice University, and Aditya Mohite, associate professor of Chemical and Biomolecular Engineering and Materials Science and Nanoengineering. Additional Rice professors will be involved as well, Cherukuri says.

"Success for us will not be papers, it will be products," Cherukuri says of what Woodside wants from the partnership. "We picked faculty at Rice in particular who were interested in taking on this charge, and they were all faculty who created companies."

Last fall, Rice announced a grant and venture initiative to accelerate innovation from Rice in the biotech space.

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This article originally ran on InnovationMap.

Rice University engineers and collaborators developed a technology that converts light into electricity. Photo by Jeff Fitlow/Rice University

Houston research team develops breakthrough process for light-harvesting crystals in DOE-backed project

solar success

A team of Rice researchers have developed a breakthrough synthesis process for developing light-harvesting materials that can be used in solar cells to convert light into electricity.

Detailed in an October study in Nature Synthesis, the new process is able to more closely control the temperature and time of the crystallization process to create 2D halide perovskites with semiconductor layers of “ideal thickness and purity,” according to a release from Rice.

The process, known as kinetically controlled space confinement, was developed by Rice University chemical and biomolecular engineer Aditya Mohite, along with others at Northwestern University, the University of Pennsylvania and the University of Rennes. The research was backed by the Department of Energy, the Army Research Office, the National Science Foundation and a number of other organizations.

“This research breakthrough is critical for the synthesis of 2D perovskites, which hold the key to achieving commercially relevant stability for solar cells and for many other optoelectronic device applications and fundamental light matter interactions,” Mohite said in a statement.

Traditional synthesis methods for creating 2D halide perovskites, which have been shown to offer a high-performance low-cost way to produce solar cells, have generated uneven crystal growth when attempting to reach a higher n value. And uneven crystal growth can result in a less reliable material, while a high n value can result in higher electrical conductivity, among other benefits.

The study shows how the kinetically controlled space confinement method can gradually increase n values in 2D halide perovskites, which will assist in the production of crystals with a certain thickness.

“We designed a way to slow down the crystallization and tune each kinetics parameter gradually to hit the sweet spot for phase-pure synthesis,” Jin Hou, a Ph.D. student at Rice and a lead author on a study, said in a statement.

The process is expected to improve the stability and lower the costs of emerging technologies in optoelectronics, or the study and application of light-emitting or light-detecting devices, and photovoltaics, the conversion of thermal energy into electricity.

"This work pushes the boundaries of higher quantum well 2D perovskites synthesis, making them a viable and stable option for a variety of applications,” Hou added.

Houston universities have been making major strides relating to crystallization processes in recent months.

In September, the University of Houston announced The Welch Foundation awarded its inaugural $5 million Catalyst for Discovery Program Grant to establish the Welch Center for Advanced Bioactive Materials Crystallization. The center will build upon UH professor Jeffrey Rimer's work relating to the use of crystals to help treat malaria and kidney stones.

Over the summer, a team of researchers at UH also published a paper detailing their discovery of how to use molecular crystals to capture large quantities of iodine, one of the most common products of radioactive fission, which is used to create nuclear energy.
Rice University engineers have created a device that absorbs light, converts it into electricity, and then uses the electricity to split water molecules and generate hydrogen. Photo courtesy Gustavo Raskoksy/Rice University

Rice University team breaks records with new sunlight-to-hydrogen device

big win

A team of Rice University engineers have developed a scalable photoelectrochemical cell that converts sunlight into clean hydrogen at a record-setting pace.

The lab led by Aditya Mohite, an associate professor at Rice, published the findings in a study in Nature Communications late last month, in collaboration with the National Renewable Energy Laboratory, which is backed by the Department of Energy. In it, the team details how they created a device that absorbs light, converts it into electricity, and then uses the electricity to split water molecules and generate hydrogen.

Austin Fehr, a chemical and biomolecular engineering doctoral student at Rice and one of the study’s lead authors, says in a statement that the device "could open up the hydrogen economy and change the way humans make things from fossil fuel to solar fuel."

The device has a high solar-to-hydrogen conversion efficiency rate of 20.8 percent, which has yet to be reached with this type of technology, according to a release from Rice. In addition to its speed, this device is groundbreaking because it uses low-cost metal-halide perovskite semiconductors to power the reaction.

A photoreactor developed by Rice University’s Mohite research group and collaborators achieved a 20.8 percent solar-to-hydrogen conversion efficiency. Photo courtesy Gustavo Raskoksy/Rice University

“Using sunlight as an energy source to manufacture chemicals is one of the largest hurdles to a clean energy economy,” Fehr says in the statement. “Our goal is to build economically feasible platforms that can generate solar-derived fuels. Here, we designed a system that absorbs light and completes electrochemical water-splitting chemistry on its surface.”

To create the device the Mohite lab turned their existing solar cell into a reactor to split water into oxygen and hydrogen. However they continued running into issues with the semiconductors being "extremely unstable in water," according to Rice.

After two years of trials and errors, the team uncovered that by adding two layers of barriers to the semiconductors they were able to reach these record-breaking efficiency rates.

The team has also shown uses for their double barrier design with different semiconductors and for different reactions.

“We hope that such systems will serve as a platform for driving a wide range of electrons to fuel-forming reactions using abundant feedstocks with only sunlight as the energy input,” Mohite says in the statement.

The device joins another game-changing product shared in a Rice research study in recent weeks. Last month, a Rice University lab led by Haotian Wang, the William Marsh Rice Trustee Chair and an associate professor at Rice, shared their findings on how their simple plug-and-play device removes carbon dioxide from air capture to induce a water-and-oxygen-based electrochemical reaction.

Rice also recently opened registration for its 20th anniversary of Energy Tech Venture Day. Click here to register for the event on Sept. 21.

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Houston's hydrogen revolution gets up to $1.2B federal boost to power Gulf Coast’s clean energy future

HyVelocity funding

The emerging low-carbon hydrogen ecosystem in Houston and along the Texas Gulf Coast is getting as much as a $1.2 billion lift from the federal government.

The U.S. Department of Energy funding, announced November 20, is earmarked for the new HyVelocity Hub. The hub — backed by energy companies, schools, nonprofits, and other organizations — will serve the country’s biggest hydrogen-producing area. The region earns that status thanks to more than 1,000 miles of dedicated hydrogen pipelines and almost 50 hydrogen production plants.

“The HyVelocity Hub demonstrates the power of collaboration in catalyzing economic growth and creating value for communities as we build a regional hydrogen economy that delivers benefits to Gulf Coast communities,” says Paula Gant, president and CEO of Des Plaines, Illinois-based GTI Energy, which is administering the hub.

HyVelocity, which aims to become the largest hydrogen hub in the country, has already received about $22 million of the $1.2 billion in federal funding to kickstart the project.

Organizers of the hydrogen project include:

  • Arlington, Virginia-based AES Corp.
  • Air Liquide, whose U.S. headquarters is in Houston
  • Chevron, which is moving its headquarters to Houston
  • Spring-based ExxonMobil
  • Lake Mary, Florida-based Mitsubishi Power Americas
  • Denmark-based Ørsted
  • Center for Houston’s Future
  • Houston Advanced Research Center
  • University of Texas at Austin

The hub’s primary contractor is HyVelocity LLC. The company says the hub could reduce carbon dioxide emissions by up to seven million metric tons per year and create as many as 45,000 over the life of the project.

HyVelocity is looking at several locations in the Houston area and along the Gulf Coast for large-scale production of hydrogen. The process will rely on water from electrolysis along with natural gas from carbon capture and storage. To improve distribution and lower storage costs, the hub envisions creating a hydrogen pipeline system.

Clean hydrogen generated by the hub will help power fuel-cell electric trucks, factories, ammonia plants, refineries, petrochemical facilities, and marine fuel operations.

Geothermal co. wins at Houston innovation event, UH secures DOE funding, and more trending energy news

top stories

Editor's note: From Sage Geosystems winning at the Houston Innovation Awards to Daikin renaming Houston's baseball stadium, these are the top headlines that resonated with EnergyCapital readers on social media and daily newsletter this week.

Local energy innovators recognized at annual Houston Innovation Awards

At an event celebrating Houston innovation, these four energy transition leaders were recognized. Photos courtesy

This week, the Houston innovation ecosystem celebrated big wins from the year, and members of the energy transition community were recognized alongside other innovators.

The Houston Innovation Awards honored over 40 finalists across categories, naming the 12 winners and honoring the two Trailblazer Legacy Awards at the event. The event, hosted at TMC Helix Park on November 14 named and celebrated the winners, which included four energy transition innovators. Continue reading.

University of Houston secures $3.6M from DOE program to fund sustainable fuel production

Researchers Rahul Pandey, senior scientist with SRI and principal investigator (left), and Praveen Bollini, a University of Houston chemical engineering faculty, are key contributors to the microreactor project. Photo via uh.edu

A University of Houston-associated project was selected to receive $3.6 million from the U.S. Department of Energy’s Advanced Research Projects Agency-Energy that aims to transform sustainable fuel production.

Nonprofit research institute SRI is leading the project “Printed Microreactor for Renewable Energy Enabled Fuel Production” or PRIME-Fuel, which will try to develop a modular microreactor technology that converts carbon dioxide into methanol using renewable energy sources with UH contributing research. Continue reading.

Global industrial company Daikin makes deal with Houston Astros on stadium rename

The Astros' stadium will have a new name in 2025. Courtesy of the Houston Astros

The Houston Astros' home will get a new name on Jan. 1, becoming Daikin Park under an agreement through the 2039 season the team announced Monday.

The stadium opened as Enron Field in 2000 as part of a 30-year, $100 million agreement but the name was removed in March 2002 following Enron Corp.'s bankruptcy filing and the ballpark briefly became Astros Field. Continue reading.

Reliant, GM Energy team up on free renewable energy EV charging

Reliant and GM Energy will be offering free nighttime charging for Chevrolet electric vehicle drivers that enroll in the new Reliant FreeCharge Nights. Photo via reliant.com

Reliant Energy and GM Energy are advancing a new renewable energy electricity plan that will “accelerate the clean energy journey for the two companies and their customers,” according to a news release.

Houston-based Reliant and GM Energy will be offering free nighttime charging for Chevrolet electric vehicle drivers that enroll in the new Reliant FreeCharge Nights. Continue reading.

Pipeline robotics: How this Houston startup is revolutionizing corrosion monitoring

Dianna Liu of ARIX Technologies joins the Houston Innovators Podcast to share her entrepreneurial journey — and why Houston was the right place to start her company. Photo courtesy of ARIX

After working for years in the downstream energy industry where safety and efficiency were top priorities, Dianna Liu thought there was a way technology could make a huge difference.

Despite loving her company and her job, she took a leap of faith to start a robotics company to create technology to more safely and efficiently monitor corrosion in pipelines. ARIX Technologies has developed software and hardware solutions for its customers with pipelines in downstream and beyond.

"Overall, this industry is an industry that really harps on doing things safely, doing things well, and having all the data to make really informed decisions," Liu says on the Houston Innovators Podcast. "Because these are huge companies with huge problems, it takes a lot of time to set up the right systems, adopt new things, and make changes." Continue reading.

CenterPoint’s Greater Houston Resiliency Initiative makes advancements on progress

step by step

CenterPoint Energy has released the first of its public progress updates on the actions being taken throughout the Greater Houston 12-county area, which is part of Phase Two of its Greater Houston Resiliency Initiative.

The GHRI Phase Two will lead to more than 125 million fewer outage minutes annually, according to CenterPoint.

According to CenterPoint, they have installed around 4,600 storm-resilient poles, installed more than 100 miles of power lines underground, cleared more than 800 miles of hazardous vegetation to improve reliability, and installed more self-healing automation all during the first two months of the program in preparation for the 2025 hurricane season.

"This summer, we accomplished a significant level of increased system hardening in the first phase of the Greater Houston Resilience Initiative,” Darin Carroll, senior vice president of CenterPoint Energy's Electric Business, says in a news release.

”Since then, as we have been fully engaged in delivering the additional set of actions in our second phase of GHRI, we continue to make significant progress as we work toward our ultimate goal of becoming the most resilient coastal grid in the country,” he continues.

The GHRI is a series of actions to “ strengthen resilience, enable a self-healing grid and reduce the duration and impact of power outages” according to a news release. The following progress through early November include:

The second phase of GHRI will run through May 31, 2025. During this time, CenterPoint teams will be installing 4,500 automated reliability devices to minimize sustained interruptions during major storms, reduce restoration times, and establish a network of 100 new weather monitoring stations. CenterPoint plans to complete each of these actions before the start of the next hurricane season.

“Now, and in the months to come, we will remain laser-focused on completing these critical resiliency actions and building the more reliable and more resilient energy system our customers expect and deserve," Carroll adds.

CenterPoint also announced that it has completed all 42 of the critical actions the company committed to taking in the aftermath of Hurricane Beryl. Some of the actions were trimming or removing higher-risk vegetation from more than 2,000 power line miles, installing more than 1,100 more storm-resilient poles, installing over 300 automated devices to reduce sustained outages, launching a new, cloud-based outage tracker, improving CenterPoint's Power Alert Service, hosting listening sessions across the service area and using feedback.

In October, CenterPoint Energy announced an agreement with Artificial Intelligence-powered infrastructure modeling platform Neara for engineering-grade simulations and analytics, and to deploy Neara’s AI capabilities across CenterPoint’s Greater Houston service area.

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