cleaning up nuclear energy

Houston research team discovers new application for crystals in nuclear energy

Radioactive waste is an obstacle to nuclear energy adoption potential. This research team from the University of Houston has discovered a potential solution. Photo via uh.edu

Researchers at the University of Houston have unlocked a new way to use crystals to safely dispose of radioactive waste.

The team of UH researchers published a paper in Cell Reports Physical Science this month detailing their discovery of how to use molecular crystals to capture large quantities of iodine, one of the most common products of radioactive fission, which is used to create nuclear energy.

According to a statement from UH, these molecular crystals are based on cyclotetrabenzil hydrazones. Ognjen Miljanic, professor of chemistry and author of the paper, and his team have created the organic molecules containing only carbon, hydrogen and oxygen atoms, which create ring-like crystals with eight smaller offshoots, earning them the nickname "The Octopus."

The discovery was made by Alexandra Robles, the first author of the study and a former doctoral student in Miljanic’s lab.

The crystals have an uptake capacity similar to that of porous metal-organic frameworks (MOFs) and covalent organic frameworks (COFs), which traditionally have been considered the “pinnacle of iodine capture materials," according to UH. They allow iodine to be moved from one area to another, are reusable and can be produced using commercially available chemicals for about $1 per gram in an academic lab.

“They are quite easy to make and can be produced at a large scale from relatively inexpensive materials without any special protective atmosphere,” Miljanic said in a statement.

The team also believes the crystals can be used to capture additional elements like carbon dioxide.

“This is a type of simple molecule that can do all sorts of different things depending on how we integrate it with the rest of any given system,” Miljanic continued. “So, we’re pursuing all those applications as well.”

Next up, Miljanic is looking to find a partner that will help the team explore practical applications and commercial aspects.

UH has been making net-zero news lately. A team of students from UH placed in the top three teams in a national competition for the Department of Energy earlier this summer. The college also shared details about its forthcoming innovation hub, which will house UH's Energy Transition Institute, as well as other centers and programs.

Joseph Powell, founding director of UH's Energy Transition Institute, sat down with EnergyCapitalHTX last week to talk about UH's vision for the organization.

Ognjen Miljanic is a University of Houston professor of chemistry and author of the paper. Photo via UH.edu

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A View From HETI

Here's 1PoinFive's newest customer on its Texas CCUS project. Photo via 1pointfive.com

Occidental Petroleum’s Houston-based carbon capture, utilization and, sequestration (CCUS) subsidiary, 1PointFive, has inked a six-year deal to sell 500,000 metric tons of carbon dioxide removal credits to software giant Microsoft.

In a news release, 1Point5 says this agreement represents the largest-ever single purchase of carbon credits enabled by direct air capture (DAC). DAC technology pulls CO2 from the air at any location, not just where carbon dioxide is emitted.

Under the agreement, the carbon dioxide that underlies the credits will be stored in a below-the-surface saline aquifer and won’t be used to produce oil or gas.

“A commitment of this magnitude further demonstrates how one of the world’s largest corporations is integrating scalable [DAC] into its net-zero strategy,” says Michael Avery, president and general manager of 1PointFive. “Energy demand across the technology industry is increasing, and we believe [DAC] is uniquely suited to remove residual emissions and further climate goals.”

Brian Marrs, senior director for carbon removal and energy at Microsoft, says DAC plays a key role in Microsoft’s effort to become carbon-negative by 2030.

The carbon dioxide will be stored at 1PointFive’s first industrial-scale DAC plant, being built near Odessa. The $1.3 billion Stratos project, which 1Point5 is developing through a joint venture with investment manager BlackRock, is designed to capture up to 500,000 metric tons of CO2 per year.

The facility is scheduled to open in mid-2025.

Aside from Microsoft, organizations that have agreed to buy carbon removal credits from 1Point5 include Amazon, Airbus, All Nippon Airways, the Houston Astros, the Houston Texans, and TD Bank.

Occidental says 1PointFive plans to set up more than 100 DAC facilities worldwide by 2035.

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