cleaning up nuclear energy

Houston research team discovers new application for crystals in nuclear energy

Radioactive waste is an obstacle to nuclear energy adoption potential. This research team from the University of Houston has discovered a potential solution. Photo via uh.edu

Researchers at the University of Houston have unlocked a new way to use crystals to safely dispose of radioactive waste.

The team of UH researchers published a paper in Cell Reports Physical Science this month detailing their discovery of how to use molecular crystals to capture large quantities of iodine, one of the most common products of radioactive fission, which is used to create nuclear energy.

According to a statement from UH, these molecular crystals are based on cyclotetrabenzil hydrazones. Ognjen Miljanic, professor of chemistry and author of the paper, and his team have created the organic molecules containing only carbon, hydrogen and oxygen atoms, which create ring-like crystals with eight smaller offshoots, earning them the nickname "The Octopus."

The discovery was made by Alexandra Robles, the first author of the study and a former doctoral student in Miljanic’s lab.

The crystals have an uptake capacity similar to that of porous metal-organic frameworks (MOFs) and covalent organic frameworks (COFs), which traditionally have been considered the “pinnacle of iodine capture materials," according to UH. They allow iodine to be moved from one area to another, are reusable and can be produced using commercially available chemicals for about $1 per gram in an academic lab.

“They are quite easy to make and can be produced at a large scale from relatively inexpensive materials without any special protective atmosphere,” Miljanic said in a statement.

The team also believes the crystals can be used to capture additional elements like carbon dioxide.

“This is a type of simple molecule that can do all sorts of different things depending on how we integrate it with the rest of any given system,” Miljanic continued. “So, we’re pursuing all those applications as well.”

Next up, Miljanic is looking to find a partner that will help the team explore practical applications and commercial aspects.

UH has been making net-zero news lately. A team of students from UH placed in the top three teams in a national competition for the Department of Energy earlier this summer. The college also shared details about its forthcoming innovation hub, which will house UH's Energy Transition Institute, as well as other centers and programs.

Joseph Powell, founding director of UH's Energy Transition Institute, sat down with EnergyCapitalHTX last week to talk about UH's vision for the organization.

Ognjen Miljanic is a University of Houston professor of chemistry and author of the paper. Photo via UH.edu

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A View From HETI

TALKE USA's Recycling Support Center opened Jan. 12 in Chambers County. Photo via LinkedIn.

TALKE USA Inc., the Houston-area arm of German logistics company TALKE, officially opened its Recycling Support Center earlier this month.

Located next to the company's Houston-area headquarters, the plant will process post-consumer plastic materials, which will eventually be converted into recycling feedstock. Chambers County partially funded the plant.

“Our new recycling support center expands our overall commitment to sustainable growth, and now, the community’s plastics will be received here before they head out for recycling. This is a win for the residents of Chambers County," Richard Heath, CEO and president of TALKE USA, said in a news release.

“The opening of our recycling support facility offers a real alternative to past obstacles regarding the large amount of plastic products our local community disposes of. For our entire team, our customers, and the Mont Belvieu community, today marks a new beginning for effective, safe, and sustainable plastics recycling.”

The new plant will receive the post-consumer plastic and form it into bales. The materials will then be processed at Cyclyx's new Houston Circularity Center, a first-of-its-kind plastic waste sorting and processing facility being developed through a joint venture between Cyclix, ExxonMobil and LyondellBasell.

“Materials collected at this facility aren’t just easy-to-recycle items like water bottles and milk jugs. All plastics are accepted, including multi-layered films—like chip bags and juice pouches. This means more of the everyday plastics used in the Chambers County community can be captured and kept out of landfills,” Leslie Hushka, chief impact officer at Cyclyx, added in a LinkedIn post.

Cyclyx's circularity center is currently under construction and is expected to produce 300 million pounds of custom-formulated feedstock annually.

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