cleaning up nuclear energy

Houston research team discovers new application for crystals in nuclear energy

Radioactive waste is an obstacle to nuclear energy adoption potential. This research team from the University of Houston has discovered a potential solution. Photo via uh.edu

Researchers at the University of Houston have unlocked a new way to use crystals to safely dispose of radioactive waste.

The team of UH researchers published a paper in Cell Reports Physical Science this month detailing their discovery of how to use molecular crystals to capture large quantities of iodine, one of the most common products of radioactive fission, which is used to create nuclear energy.

According to a statement from UH, these molecular crystals are based on cyclotetrabenzil hydrazones. Ognjen Miljanic, professor of chemistry and author of the paper, and his team have created the organic molecules containing only carbon, hydrogen and oxygen atoms, which create ring-like crystals with eight smaller offshoots, earning them the nickname "The Octopus."

The discovery was made by Alexandra Robles, the first author of the study and a former doctoral student in Miljanic’s lab.

The crystals have an uptake capacity similar to that of porous metal-organic frameworks (MOFs) and covalent organic frameworks (COFs), which traditionally have been considered the “pinnacle of iodine capture materials," according to UH. They allow iodine to be moved from one area to another, are reusable and can be produced using commercially available chemicals for about $1 per gram in an academic lab.

“They are quite easy to make and can be produced at a large scale from relatively inexpensive materials without any special protective atmosphere,” Miljanic said in a statement.

The team also believes the crystals can be used to capture additional elements like carbon dioxide.

“This is a type of simple molecule that can do all sorts of different things depending on how we integrate it with the rest of any given system,” Miljanic continued. “So, we’re pursuing all those applications as well.”

Next up, Miljanic is looking to find a partner that will help the team explore practical applications and commercial aspects.

UH has been making net-zero news lately. A team of students from UH placed in the top three teams in a national competition for the Department of Energy earlier this summer. The college also shared details about its forthcoming innovation hub, which will house UH's Energy Transition Institute, as well as other centers and programs.

Joseph Powell, founding director of UH's Energy Transition Institute, sat down with EnergyCapitalHTX last week to talk about UH's vision for the organization.

Ognjen Miljanic is a University of Houston professor of chemistry and author of the paper. Photo via UH.edu

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A View From HETI

The company plans to use the funds to support its flagship Texas facility and planned merger. Photo via LinkedIn

Houston-based Ace Green Recycling has raised $32 million in private investment in public equity (PIPE) financing to support its future plans for growth.

The battery recycling technology company secured the financing with Athena Technology Acquisition Corp. II, a publicly traded special purpose acquisition company that Ace previously announced it plans to merge with. Once the merger is completed, Ace will become a publicly traded company on the Nasdaq Stock Exchange under the ticker symbol "AGXI."

Ace says the financing will be used to complete the merger and scale the company.

“This investment accelerates our mission to redefine battery recycling at a global scale,” Ace CEO Nischay Chadha said in a news release. “At Ace, we are deploying Greenlead® and LithiumFirst™ as a new standard–fully electrified, Scope 1 emissions-free solutions designed to replace legacy processes and unlock a cleaner supply chain for critical materials. We believe that the future of electrification depends on how efficiently and sustainably we recover these resources, and this milestone brings us meaningfully closer to that future.”

Ace says the funding will also be primarily used to fund capital expenditures related to the development of its planned flagship recycling facility, located outside of Beaumont, Texas. According to a February investor presentation, the facility is expected to launch in 2027. It will recycle lead-acid and lithium-ion batteries.

Ace agreed to a 15-year battery material supply agreement with Miami-based OM Commodities last year, in which OM Commodities would supply Ace with at least 30,000 metric tons of lead scrap to be recycled annually. Switzerland-based Glencore plc agreed to a 15-year offtake agreement to purchase up to 100 percent of ACE’s products from four of its planned lead-acid and lithium-ion battery recycling parks back in 2022.

Ace also reported that the funding will be put toward "supporting the expansion of operations and to fund the purchase of other companies," in the release.

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