cleaning up nuclear energy

Houston research team discovers new application for crystals in nuclear energy

Radioactive waste is an obstacle to nuclear energy adoption potential. This research team from the University of Houston has discovered a potential solution. Photo via uh.edu

Researchers at the University of Houston have unlocked a new way to use crystals to safely dispose of radioactive waste.

The team of UH researchers published a paper in Cell Reports Physical Science this month detailing their discovery of how to use molecular crystals to capture large quantities of iodine, one of the most common products of radioactive fission, which is used to create nuclear energy.

According to a statement from UH, these molecular crystals are based on cyclotetrabenzil hydrazones. Ognjen Miljanic, professor of chemistry and author of the paper, and his team have created the organic molecules containing only carbon, hydrogen and oxygen atoms, which create ring-like crystals with eight smaller offshoots, earning them the nickname "The Octopus."

The discovery was made by Alexandra Robles, the first author of the study and a former doctoral student in Miljanic’s lab.

The crystals have an uptake capacity similar to that of porous metal-organic frameworks (MOFs) and covalent organic frameworks (COFs), which traditionally have been considered the “pinnacle of iodine capture materials," according to UH. They allow iodine to be moved from one area to another, are reusable and can be produced using commercially available chemicals for about $1 per gram in an academic lab.

“They are quite easy to make and can be produced at a large scale from relatively inexpensive materials without any special protective atmosphere,” Miljanic said in a statement.

The team also believes the crystals can be used to capture additional elements like carbon dioxide.

“This is a type of simple molecule that can do all sorts of different things depending on how we integrate it with the rest of any given system,” Miljanic continued. “So, we’re pursuing all those applications as well.”

Next up, Miljanic is looking to find a partner that will help the team explore practical applications and commercial aspects.

UH has been making net-zero news lately. A team of students from UH placed in the top three teams in a national competition for the Department of Energy earlier this summer. The college also shared details about its forthcoming innovation hub, which will house UH's Energy Transition Institute, as well as other centers and programs.

Joseph Powell, founding director of UH's Energy Transition Institute, sat down with EnergyCapitalHTX last week to talk about UH's vision for the organization.

Ognjen Miljanic is a University of Houston professor of chemistry and author of the paper. Photo via UH.edu

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A View From HETI

The first phase of 1PointFive's major direct air capture project is expected to come online in Q2. Photo via 1pointfive.com

Houston-based 1PointFive, a subsidiary of Occidental Petroleum Corp., has secured another buyer of carbon dioxide removal credits for its $1.3 billion STRATOS project as it moves toward operation.

Bain & Company, a Boston-based consulting firm, has agreed to purchase 9,000 metric tons of carbon dioxide removal (CDR) credits from the direct air capture (DAC) facility over three years, according to a news release. DAC technology pulls CO2 from the air at any location, not just where carbon dioxide is emitted.

The deal is Bain's first purchase of DAC removal credits. The company has developed a program that helps clients purchase carbon credits from a range of carbon-removal technologies.

"We are proud to partner with 1PointFive and add them to our portfolio of engineered carbon removal technologies," Sam Israelit, Bain’s chief sustainability officer, said in the news release. "Their track record for developing DAC technology, coupled with their deep understanding of what it takes to deliver large-scale infrastructure projects, uniquely positions them to be a leader in this emerging segment.”

“We believe this agreement demonstrates continued momentum for the solution while supporting the development of vital domestic infrastructure,” Anthony Cottone, president and general manager of 1PointFive, added in the release.

Bain joins others like Microsoft, Amazon, AT&T, Airbus, the Houston Astros and the Houston Texans that have agreed to buy CDR credits from STRATOS.

The Texas-based STRATOS project is being developed through a joint venture with investment manager BlackRock and is designed to capture up to 500,000 metric tons of CO2 per year. The U.S Environmental Protection Agency approved Class VI permits for the project last year.

1PointFive says STRATOS is "progressing through start-up activities." The company shared in a LinkedIn post that Phase 1 of the project is expected to go online in Q2, with Phase 2 ramping up through the remainder of 2026.

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