cleaning up nuclear energy

Houston research team discovers new application for crystals in nuclear energy

Radioactive waste is an obstacle to nuclear energy adoption potential. This research team from the University of Houston has discovered a potential solution. Photo via uh.edu

Researchers at the University of Houston have unlocked a new way to use crystals to safely dispose of radioactive waste.

The team of UH researchers published a paper in Cell Reports Physical Science this month detailing their discovery of how to use molecular crystals to capture large quantities of iodine, one of the most common products of radioactive fission, which is used to create nuclear energy.

According to a statement from UH, these molecular crystals are based on cyclotetrabenzil hydrazones. Ognjen Miljanic, professor of chemistry and author of the paper, and his team have created the organic molecules containing only carbon, hydrogen and oxygen atoms, which create ring-like crystals with eight smaller offshoots, earning them the nickname "The Octopus."

The discovery was made by Alexandra Robles, the first author of the study and a former doctoral student in Miljanic’s lab.

The crystals have an uptake capacity similar to that of porous metal-organic frameworks (MOFs) and covalent organic frameworks (COFs), which traditionally have been considered the “pinnacle of iodine capture materials," according to UH. They allow iodine to be moved from one area to another, are reusable and can be produced using commercially available chemicals for about $1 per gram in an academic lab.

“They are quite easy to make and can be produced at a large scale from relatively inexpensive materials without any special protective atmosphere,” Miljanic said in a statement.

The team also believes the crystals can be used to capture additional elements like carbon dioxide.

“This is a type of simple molecule that can do all sorts of different things depending on how we integrate it with the rest of any given system,” Miljanic continued. “So, we’re pursuing all those applications as well.”

Next up, Miljanic is looking to find a partner that will help the team explore practical applications and commercial aspects.

UH has been making net-zero news lately. A team of students from UH placed in the top three teams in a national competition for the Department of Energy earlier this summer. The college also shared details about its forthcoming innovation hub, which will house UH's Energy Transition Institute, as well as other centers and programs.

Joseph Powell, founding director of UH's Energy Transition Institute, sat down with EnergyCapitalHTX last week to talk about UH's vision for the organization.

Ognjen Miljanic is a University of Houston professor of chemistry and author of the paper. Photo via UH.edu

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A View From HETI

Yara North America is growing its Texas footprint. Photo courtesy Yara International

Yara North America, a subsidiary of Norwegian fertilizer and ammonia producer Yara International, has agreed to buy an ammonia production plant in Texas City for $1.3 billion.

The seller is GCA Holdings, an affiliate of Texas City-based chemical manufacturer Gulf Coast Ammonia, which is owned by private equity firms Lotus Infrastructure Partners and MB Energy.

The Texas City plant, with an eventual annual capacity of 1.3 million metric tons, is expected to start full production by the end of this year. Yara says the ammonia produced by the plant will serve its own fertilizer production system and its key customers.

During a recent call with analysts and investors, Magnus Ankarstrand, executive vice president and CFO of Yara International, said the plant holds the potential to become one of the company’s most profitable plants. The $1.3 billion purchase price, he added, “is a very attractive entry ticket to ammonia production in the U.S. at a very attractive cost.”

The Texas City plant will add to Yara’s holdings in the Lone Star State, as Yara is the majority owner of an ammonia, hydrogen and nitrogen production plant in Freeport.

Construction of the ammonia plant began in 2020, but technical and infrastructure issues delayed the project. On its website, Gulf Coast Ammonia says the plant represented a $600 million investment.

“Gulf Coast Ammonia is a world-class asset that required disciplined execution across development, financing, construction, and commercial structuring,” Philipp Pletka, managing director of Lotus Infrastructure Partners, says in a news release.

Trexlertown, Pennsylvania-based Air Products, which owns and operates the country’s largest hydrogen pipeline network, will continue to supply hydrogen and nitrogen for the plant under a long-term deal with Yara, according to the release.

However, the news comes two days after Yara International announced that it would no longer be purchasing ammonia assets in the Louisiana Clean Energy Complex (LCEC) from Air Products. In a separate release, Yara said it planned to reallocate funds toward "alternative mature U.S. ammonia investment opportunities with more competitive returns."

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