planting climate change impact

Research team lands DOE grant to investigate carbon storage in soil

Two Rice University researchers just received DOE funding for carbon storage research. Photo by Gustavo Raskosky/Rice University

Two researchers at Rice University are digging into how soil is formed with hopes to better understand carbon storage and potential new methods for combating climate change.

Backed by a three-year grant from the Department of Energy, the research is led by Mark Torres, an assistant professor of Earth, environmental and planetary sciences; and Evan Ramos, a postdoctoral fellow in the Torres lab. Co-investigators include professors and scientists with the Brown University, University of Massachusetts Amherst and Lawrence Berkeley National Laboratory.

According to a release from Rice, the team aims to investigate the processes that allow soil to store roughly three times as much carbon as organic matter compared to Earth's atmosphere.

“Maybe there’s a way to harness Earth’s natural mechanisms of sequestering carbon to combat climate change,” Torres said in a statement. “But to do that, we first have to understand how soils actually work.”

The team will analyze samples collected from different areas of the East River watershed in Colorado. Prior research has shown that rivers have been great resources for investigating chemical reactions that have taken place as soil is formed. Additionally, research supports that "clay plays a role in storing carbon derived from organic sources," according to Rice.

"We want to know when and how clay minerals form because they’re these big, platy, flat minerals with a high surface area that basically shield the organic carbon in the soil," Ramos said in the statement. "We think they protect that organic carbon from breakdown and allow it to grow in abundance.”

Additionally, the researchers plan to create a model that better quantifies the stabilization of organic carbon over time. According to Torres, the model could provide a basis for predicting carbon dioxide changes in Earth's atmosphere.

"We’re trying to understand what keeps carbon in soils, so we can get better at factoring in their role in climate models and render predictions of carbon dioxide changes in the atmosphere more detailed and accurate,” Torres explained in the statement.

The DOE and Rice have partnered on a number of projects related to the energy transition in recent months. Last week, Rice announced that it would host the Carbon Management Community Summit this fall, sponsored by the DOE, and in partnership with the city of Houston and climate change-focused multimedia company Climate Now.

In July the DOE announced $100 million in funding for its SCALEUP program at an event for more than 100 energy innovators at the university.

Rice also recently opened its 250,000-square-foot Ralph S. O’Connor Building for Engineering and Science. The state-of-the-art facility is the new home for four key research areas at Rice: advanced materials, quantum science and computing, urban research and innovation, and the energy transition.

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A View From HETI

Rice University scientists' “recharge-to-recycle” reactor has major implications for the electric vehicle sector. Photo courtesy Jorge Vidal/Rice University.

Engineers at Rice University have developed a cleaner, innovative process to turn end-of-life lithium-ion battery waste into new lithium feedstock.

The findings, recently published in the journal Joule, demonstrate how the team’s new “recharge-to-recycle” reactor recharges the battery’s waste cathode materials to coax out lithium ions into water. The team was then able to form high-purity lithium hydroxide, which was clean enough to feed directly back into battery manufacturing.

The study has major implications for the electric vehicle sector, which significantly contributes to the waste stream from end-of-life battery packs. Additionally, lithium tends to be expensive to mine and refine, and current recycling methods are energy- and chemical-intensive.

“Directly producing high-purity lithium hydroxide shortens the path back into new batteries,” Haotian Wang, associate professor of chemical and biomolecular engineering, co-corresponding author of the study and co-founder of Solidec, said in a news release. “That means fewer processing steps, lower waste and a more resilient supply chain.”

Sibani Lisa Biswal, chair of Rice’s Department of Chemical and Biomolecular Engineering and the William M. McCardell Professor in Chemical Engineering, also served as co-corresponding author on the study.

“We asked a basic question: If charging a battery pulls lithium out of a cathode, why not use that same reaction to recycle?” Biswal added in the release. “By pairing that chemistry with a compact electrochemical reactor, we can separate lithium cleanly and produce the exact salt manufacturers want.”

The new process also showed scalability, according to Rice. The engineers scaled the device to 20 square centimeters, then ran a 1,000-hour stability test and processed 57 grams of industrial black mass supplied by industry partner Houston-based TotalEnergies. The results produced lithium hydroxide that was more than 99 percent pure. It also maintained an average lithium recovery rate of nearly 90 percent over the 1,000-hour test, showing its durability. The process also worked across multiple battery chemistries, including lithium iron phosphate, lithium manganese oxide and nickel-manganese-cobalt variants.

Looking ahead, the team plans to scale the process and consider ways it can sustain high efficiency for greater lithium hydroxide concentrations.

“We’ve made lithium extraction cleaner and simpler,” Biswal added in the release. “Now we see the next bottleneck clearly. Tackle concentration, and you unlock even better sustainability.

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