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Rice University and UH labs team up to improve emerging carbon capture technique

new findings

New research from Rice and UH has helped boost the lifespan of CO2RR systems, a newer technology used for carbon capture. Photo via htxenergytransition.org

A team of researchers led by professors from two Houston universities has discovered new methods that help stabilize an emerging technique known as carbon dioxide reduction reaction, or CO2RR, that is used for carbon capture and utilization processes.

The team led by Rice University’s Haotian Wang, associate professor in chemical and biomolecular engineering, and Xiaonan Shan, associate professor of electrical and computer engineering at University of Houston, published its findings in a recent edition of the journal Nature Energy.

CO2RR is an emerging carbon capture and utilization technique where electricity and chemical catalysts are used to convert carbon dioxide gas into carbon-containing compounds like alcohols, ethylene, formic acids or carbon monoxide, according to a news release from Rice. The result can be used as fuels, chemicals or as starting materials to produce other compounds.

The technology is used in commercial membrane electrode assembly (MEA) electrolyzers to convert carbon dioxide into valuable compounds, but the technology isn’t perfected. A significant challenge in CO2RR technology has been the accumulation of bicarbonate salt crystals on the backside of the cathode gas diffusion electrode and within the gas flow channels. The salt precipitates block the flow of carbon dioxide gas through the cathode chamber, which reduce the performance and can cause a failure of the electrolyzers.

The goal in the study was to understand why and how bicarbonate salts form during this reaction. The Rice and UH teams worked together using operando Raman spectroscopy, which is a technique that allows researchers to study the structure of materials and any precipitates that adhere to them while the device is functioning.

“By utilizing operando Raman spectroscopy and optical microscopy, we successfully tracked the movement of bicarbonate-containing droplets and identified their migration pattern,” Shan said in the release. “This provided us the information to develop an effective strategy to manage these droplets without interrupting system stability.”

Next, the team worked to prevent the salt crystals from forming. First, they tested lowering the concentration of cations, like sodium or potassium, in the electrolyte to slow down the salt formation. This method proved to be effective.

They also coated the cathode with parylene, a synthetic polymer that repels water, like Teflon, which also notably improved the stability of the electrolyzer and prevented salt accumulation.

“Inspired by the waxy surface of the lotus leaf which causes water droplets to bead up and roll off, carrying off any dirt particles with it and leaving the leaf’s surface clean, we wondered if coating the gas flow channel with a nonstick substance will prevent salt-laden droplets from staying on the surface of the electrodes for too long and, therefore, reduce salt buildup.” Wang said in the release.

According to Wang, these relatively simple discoveries can extend the operational lifespan of CO2RR systems from a few hundred hours to over 1,000 hours.

The findings also have major implications for commercial applications, Shan added.

“This advancement paves the way for longer-lasting and more reliable (CO2RR) systems, making the technology more practical for large-scale chemical manufacturing,” Shan said in the release. “The improvements we developed are crucial for transitioning CO2 electrolysis from laboratory setups to commercial applications for producing sustainable fuels and chemicals.”

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Rice professor and Solidec co-founder Haotian Wang's research enables CO2 to be converted into valuable chemicals and fuels. Photo courtesy Welch Foundation.

Houston clean energy pioneer earns prestigious Welch Foundation award

Awards Season

A Rice University professor has earned a prestigious award from the Houston-based Welch Foundation, which supports chemistry research.

The foundation gave its 2025 Norman Hackerman Award in Chemical Research to Haotian Wang for his “exceptionally creative” research involving carbon dioxide electrochemistry. His research enables CO2 to be converted into valuable chemicals and fuels.

The award included $100,000 and a bronze sculpture.

“Dr. Wang’s extensive body of work and rigorous pursuit of efficient electrochemical solutions to practical problems set him apart as a top innovator among early-career researchers,” Catherine Murphy, chairwoman of the foundation’s Scientific Advisory Board, said in a news release.

Wang is an associate professor in the Department of Chemical and Biomolecular Engineering at Rice. The department’s Wang Group develops nanomaterials and electrolyzers for energy and environmental uses, such as energy storage, chemical and fuel generation, green synthesis and water treatment.

Wang also is co-founder of Solidec, a Houston startup that aims to turn his innovations into low-carbon fuels, carbon-negative hydrogen and carbon-neutral peroxide. The startup extracts molecules from water and air, then transforms them into pure chemicals and fuels that are free of carbon emissions.

Solidec has been selected for Chevron Technology Ventures’ catalyst program, a Rice One Small Step grant, a U.S. Department of Energy grant, and the first cohort of the Activate Houston program.

“Dr. Wang’s use of electrochemistry to close the carbon cycle and develop renewable sources of industrial chemicals directly intersects with the Welch Foundation mission of advancing chemistry while improving life,” Fred Brazelton, chairman and director of the Welch Foundation, said in the release.

Ramamoorthy Ramesh, executive vice president for research at Rice University, added: “We are proud to (Dr. Wang) at Rice. He’s using chemical engineering to solve a big problem for humanity, everything that the Welch Foundation stands for.”

Last year, the Hackerman Award went to Baylor College of Medicine's Livia Schiavinato Eberlin, who's known for her groundbreaking work in the application of mass spectrometry technologies, which are changing how physicians treat cancer and analyze tissues. Read more here.

Led by Haotian Wang (left) and Feng-Yang Chen, the Rice University team published a study this month detailing how its reactor system sustainably converts waste into ammonia. Photo by Jeff Fitlow/Rice University

Houston lab develops reactor that sustainably turns waste into ammonia

seeing green

A team of Rice University engineers has developed a reactor design that can decarbonize ammonia production, produce clean water and potentially have applications in further research into other eco-friendly chemical processes.

Led by Rice associate professor Haotian Wang, the team published a study this month in the journal Nature Catalysis that details how the new reactor system sustainably and efficiently converts nitrates (common pollutants found in industrial wastewater and agricultural runoff) into ammonia, according to the university. The research was supported by Rice and the National Science Foundation.

“Our findings suggest a new, greener method of addressing both water pollution and ammonia production, which could influence how industries and communities handle these challenges,” Wang says in a statement. “If we want to decarbonize the grid and reach net-zero goals by 2050, there is an urgent need to develop alternative ways to produce ammonia sustainably.”

Other methods of creating ammonia include the Haber-Bosh process and electrochemical synthesis. The Haber-Bosh process requires large-scale centralized infrastructure and high temperature and pressure conditions. Meanwhile, electrochemical synthesis requires a high concentration of additive chemicals.

According to Rice, the new reactor requires less additive chemicals than the electrochemical synthesis, allowing nitrates to be converted more sustainably. The reactor relies on an innovative porous solid electrolyte as well as recyclable ions and a three-chamber system to improve the reaction’s efficiency.

Additionally, this development provides an effective water decontamination method.

“We conducted experiments where we flowed nitrate-contaminated water through this reactor and measured the amount of ammonia produced and the purity of the treated water,” Feng-Yang Chen, a Rice graduate student who is the lead author on the study, says. “We discovered that our novel reactor system could turn nitrate-contaminated water into pure ammonia and clean water very efficiently, without the need for extra chemicals. In simple terms, you put wastewater in, and you get pure ammonia and purified water out.”

Pedro Alvarez, the George R. Brown Professor of Civil and Environmental Engineering, director of the Nanosystems Engineering Research Center for Nanotechnology-Enabled Water Treatment (NEWT) and the Water Technologies Entrepreneurship and Research (WaTER) Institute at Rice, says the reactor is "very timely and important" for growing cities that must deal with nitrate-contaminated groundwater supplies it.

"Conventional nitrate removal in drinking water treatment involves ion exchange or membrane filtration by reverse osmosis, which generates brines and transfers the nitrate problem from one phase to another,” he continues.

Wang's lab has been making headlines in recent years for innovative processes and technologies focused on the energy transition.

Last year, the lab published a study in Nature detailing a new technology that uses electricity to remove carbon dioxide from air capture to induce a water-and-oxygen-based electrochemical reaction, generating between 10 to 25 liters of high-purity carbon using only the power of a standard lightbulb.

In 2022, Rice reported that Wang’s lab in the George R. Brown School of Engineering had also replaced rare, expensive iridium with ruthenium, a more abundant precious metal, as the positive-electrode catalyst in a reactor that splits water into hydrogen and oxygen.

The lab received a portion of $10.8 million in research grants from the Houston-based Welch Foundation for research focused on converting carbon dioxide into useful chemicals, such as ethanol, last year. And Solidec, founded by Ryan Duchanois and Yang Xia from Wang's Lab, also received a $100,000 award from Rice as part of the One Small Step Grant program.

Wang has also been named among one of the most-cited researchers in the world.
Peng Zhu (left) and Haotian Wang developed a carbon-capture device prototype. Photos courtesy Jeff Fitlow/Rice University

Rice scientists develop simple but game-changing carbon capture device

small scale, big impact

A Rice University lab has developed an efficient, scalable way to capture carbon dioxide — and it just needs to be plugged into a power outlet to work.

The new technology developed in the lab of chemical and biomolecular engineer Haotian Wang, the William Marsh Rice Trustee Chair and an associate professor at Rice, uses electricity to remove carbon dioxide from air capture to induce a water-and-oxygen-based electrochemical reaction. The findings were shared in a study published in Nature last month.

Traditionally, carbon capture requires very energy intensive processes that need high temperatures and for the carbon that's been captured to be regenerated. The process also often requires large-scale infrastructure.

In the Wang lab's method, the small reactor can continuously remove carbon dioxide from a simulated flue gas with nearly 100 percent efficiency, generating between 10 to 25 liters of high-purity carbon using only the power of a standard lightbulb, according to a statement from Rice.

It does not create or consume chemicals, nor does it need to be heated up or pressurized, according to Wang. And it only requires a simple power source.

"The technology can be scaled up to industrial settings—power plants, chemical plants—but the great thing about it is that it allows for small-scale use as well: I can even use it in my office,” Wang says in the statement. “We could, for example, pull carbon dioxide from the atmosphere and continuously inject that concentrated gas into a greenhouse to stimulate plant growth. We’ve heard from space technology companies interested in using the device on space stations to remove the carbon dioxide astronauts exhale.”

Wang and lab member Peng Zhu, a chemical and biomolecular engineering graduate student at Rice and lead author on the study, initially made the discovery when working on an earlier version of the reactor intended for carbon dioxide utilization.

During this process Zhu noticed that gas bubbles flowed out of the reactor’s middle chamber when producing liquid products like acetic acid and formic acid, and that the number of bubbles would increase when more current was applied to the reactor.

This led the scientists to realize that the reactor was creating carbonate ions that were converted into a continuous flow of high-purity carbon dioxide after passing through the reactor's solid-electrolyte layer.

“Scientific discovery often requires this patient, continuous observation and the curiosity to learn what’s really going on, the choice not to neglect those phenomena that don’t necessarily fit in the experimental frame," Wang said in a statement.

A number of players in the Houston area have been making headway in carbon capture space in recent weeks.

Earlier this summer, the U.S. Department of Energy granted more than $45 million in federal funding to four Houston companies to promote the capture, transportation, use, and storage of tons of carbon dioxide emissions.

The Rice Alliance also recently named 15 startups to its Clean Energy Accelerator. A number of the fledgling companies are focused on carbon management and capture.

Video by Brandon Martin/Rice University

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UH's $44 million mass timber building slashed energy use in first year

building up

The University of Houston recently completed assessments on year one of the first mass timber project on campus, and the results show it has had a major impact.

Known as the Retail, Auxiliary, and Dining Center, or RAD Center, the $44 million building showed an 84 percent reduction in predicted energy use intensity, a measure of how much energy a building uses relative to its size, compared to similar buildings. Its Global Warming Potential rating, a ratio determined by the Intergovernmental Panel on Climate Change, shows a 39 percent reduction compared to the benchmark for other buildings of its type.

In comparison to similar structures, the RAD Center saved the equivalent of taking 472 gasoline-powered cars driven for one year off the road, according to architecture firm Perkins & Will.

The RAD Center was created in alignment with the AIA 2030 Commitment to carbon-neutral buildings, designed by Perkins & Will and constructed by Houston-based general contractor Turner Construction.

Perkins & Will’s work reduced the building's carbon footprint by incorporating lighter mass timber structural systems, which allowed the RAD Center to reuse the foundation, columns and beams of the building it replaced. Reused elements account for 45 percent of the RAD Center’s total mass, according to Perkins & Will.

Mass timber is considered a sustainable alternative to steel and concrete construction. The RAD Center, a 41,000-square-foot development, replaced the once popular Satellite, which was a food, retail and hangout center for students on UH’s campus near the Science & Research Building 2 and the Jack J. Valenti School of Communication.

The RAD Center uses more than a million pounds of timber, which can store over 650 metric tons of CO2. Aesthetically, the building complements the surrounding campus woodlands and offers students a view both inside and out.

“Spaces are designed to create a sense of serenity and calm in an ecologically-minded environment,” Diego Rozo, a senior project manager and associate principal at Perkins & Will, said in a news release. “They were conceptually inspired by the notion of ‘unleashing the senses’ – the design celebrating different sights, sounds, smells and tastes alongside the tactile nature of the timber.”

In addition to its mass timber design, the building was also part of an Energy Use Intensity (EUI) reduction effort. It features high-performance insulation and barriers, natural light to illuminate a building's interior, efficient indoor lighting fixtures, and optimized equipment, including HVAC systems.

The RAD Center officially opened Phase I in Spring 2024. The third and final phase of construction is scheduled for this summer, with a planned opening set for the fall.

Experts on U.S. energy infrastructure, sustainability, and the future of data

Guest column

Digital infrastructure is the dominant theme in energy and infrastructure, real estate and technology markets.

Data, the byproduct and primary value generated by digital infrastructure, is referred to as “the fifth utility,” along with water, gas, electricity and telecommunications. Data is created, aggregated, stored, transmitted, shared, traded and sold. Data requires data centers. Data centers require energy. The United States is home to approximately 40% of the world's data centers. The U.S. is set to lead the world in digital infrastructure advancement and has an opportunity to lead on energy for a very long time.

Data centers consume vast amounts of electricity due to their computational and cooling requirements. According to the United States Department of Energy, data centers consume “10 to 50 times the energy per floor space of a typical commercial office building.” Lawrence Berkeley National Laboratory issued a report in December 2024 stating that U.S. data center energy use reached 176 TWh by 2023, “representing 4.4% of total U.S. electricity consumption.” This percentage will increase significantly with near-term investment into high performance computing (HPC) and artificial intelligence (AI). The markets recognize the need for digital infrastructure build-out and, developers, engineers, investors and asset owners are responding at an incredible clip.

However, the energy demands required to meet this digital load growth pose significant challenges to the U.S. power grid. Reliability and cost-efficiency have been, and will continue to be, two non-negotiable priorities of the legal, regulatory and quasi-regulatory regime overlaying the U.S. power grid.

Maintaining and improving reliability requires physical solutions. The grid must be perfectly balanced, with neither too little nor too much electricity at any given time. Specifically, new-build, physical power generation and transmission (a topic worthy of another article) projects must be built. To be sure, innovative financial products such as virtual power purchase agreements (VPPAs), hedges, environmental attributes, and other offtake strategies have been, and will continue to be, critical to growing the U.S. renewable energy markets and facilitating the energy transition, but the U.S. electrical grid needs to generate and move significantly more electrons to support the digital infrastructure transformation.

But there is now a third permanent priority: sustainability. New power generation over the next decade will include a mix of solar (large and small scale, offsite and onsite), wind and natural gas resources, with existing nuclear power, hydro, biomass, and geothermal remaining important in their respective regions.

Solar, in particular, will grow as a percentage of U.S grid generation. The Solar Energy Industries Association (SEIA) reported that solar added 50 gigawatts of new capacity to the U.S. grid in 2024, “the largest single year of new capacity added to the grid by an energy technology in over two decades.” Solar is leading, as it can be flexibly sized and sited.

Under-utilized technology such as carbon capture, utilization and storage (CCUS) will become more prominent. Hydrogen may be a potential game-changer in the medium-to-long-term. Further, a nuclear power renaissance (conventional and small modular reactor (SMR) technologies) appears to be real, with recent commitments from some of the largest companies in the world, led by technology companies. Nuclear is poised to be a part of a “net-zero” future in the United States, also in the medium-to-long term.

The transition from fossil fuels to zero carbon renewable energy is well on its way – this is undeniable – and will continue, regardless of U.S. political and market cycles. Along with reliability and cost efficiency, sustainability has become a permanent third leg of the U.S. power grid stool.

Sustainability is now non-negotiable. Corporate renewable and low carbon energy procurement is strong. State renewable portfolio standards (RPS) and clean energy standards (CES) have established aggressive goals. Domestic manufacturing of the equipment deployed in the U.S. is growing meaningfully and in politically diverse regions of the country. Solar, wind and batteries are increasing less expensive. But, perhaps more importantly, the grid needs as much renewable and low carbon power generation as possible - not in lieu of gas generation, but as an increasingly growing pairing with gas and other technologies. This is not an “R” or “D” issue (as we say in Washington), and it's not an “either, or” issue, it's good business and a physical necessity.

As a result, solar, wind and battery storage deployment, in particular, will continue to accelerate in the U.S. These clean technologies will inevitably become more efficient as the buildout in the U.S. increases, investments continue and technology advances.

At some point in the future (it won’t be in the 2020s, it could be in the 2030s, but, more realistically, in the 2040s), the U.S. will have achieved the remarkable – a truly modern (if not entirely overhauled) grid dependent largely on a mix of zero and low carbon power generation and storage technology. And when this happens, it will have been due in large part to the clean technology deployment and advances over the next 10 to 15 years resulting from the current digital infrastructure boom.

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Hans Dyke and Gabbie Hindera are lawyers at Bracewell. Dyke's experience includes transactions in the electric power and oil and gas midstream space, as well as transactions involving energy intensive industries such as data storage. Hindera focuses on mergers and acquisitions, joint ventures, and public and private capital market offerings.

Rice researchers' quantum breakthrough could pave the way for next-gen superconductors

new findings

A new study from researchers at Rice University, published in Nature Communications, could lead to future advances in superconductors with the potential to transform energy use.

The study revealed that electrons in strange metals, which exhibit unusual resistance to electricity and behave strangely at low temperatures, become more entangled at a specific tipping point, shedding new light on these materials.

A team led by Rice’s Qimiao Si, the Harry C. and Olga K. Wiess Professor of Physics and Astronomy, used quantum Fisher information (QFI), a concept from quantum metrology, to measure how electron interactions evolve under extreme conditions. The research team also included Rice’s Yuan Fang, Yiming Wang, Mounica Mahankali and Lei Chen along with Haoyu Hu of the Donostia International Physics Center and Silke Paschen of the Vienna University of Technology. Their work showed that the quantum phenomenon of electron entanglement peaks at a quantum critical point, which is the transition between two states of matter.

“Our findings reveal that strange metals exhibit a unique entanglement pattern, which offers a new lens to understand their exotic behavior,” Si said in a news release. “By leveraging quantum information theory, we are uncovering deep quantum correlations that were previously inaccessible.”

The researchers examined a theoretical framework known as the Kondo lattice, which explains how magnetic moments interact with surrounding electrons. At a critical transition point, these interactions intensify to the extent that the quasiparticles—key to understanding electrical behavior—disappear. Using QFI, the team traced this loss of quasiparticles to the growing entanglement of electron spins, which peaks precisely at the quantum critical point.

In terms of future use, the materials share a close connection with high-temperature superconductors, which have the potential to transmit electricity without energy loss, according to the researchers. By unblocking their properties, researchers believe this could revolutionize power grids and make energy transmission more efficient.

The team also found that quantum information tools can be applied to other “exotic materials” and quantum technologies.

“By integrating quantum information science with condensed matter physics, we are pivoting in a new direction in materials research,” Si said in the release.

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