Houston chemist earns $12M grant to support innovative soil pollutant removal process

making moves

James Tour of Rice University has received funding to support his energy transition research. Photo via rice.edu

A Rice University chemist James Tour has secured a new $12 million cooperative agreement with the U.S. Army Engineer Research and Development Center on the team’s work to efficiently remove pollutants from soil.

The four-year agreement will support the team’s ongoing work on removing per- and polyfluoroalkyl substances (PFAS) from contaminated soil through its rapid electrothermal mineralization (REM) process, according to a statement from Rice.

Traditionally PFAS have been difficult to remove by conventional methods. However, Tour and the team of researchers have been developing this REM process, which heats contaminated soil to 1,000 C in seconds and converts it into nontoxic calcium fluoride efficiently while also preserving essential soil properties.

“This is a substantial improvement over previous methods, which often suffer from high energy and water consumption, limited efficiency and often require the soil to be removed,” Tour said in the statement.

The funding will help Tour and the team scale the innovative REM process to treat large volumes of soil. The team also plans to use the process to perform urban mining of electronic and industrial waste and further develop a “flash-within-flash” heating technology to synthesize materials in bulk, according to Rice.

“This research advances scientific understanding but also provides practical solutions to critical environmental challenges, promising a cleaner, safer world,” Christopher Griggs, a senior research physical scientist at the ERDC, said in the statement.

Also this month, Tour and his research team published a report in Nature Communications detailing another innovative heating technique that can remove purified active materials from lithium-ion battery waste, which can lead to a cleaner production of electric vehicles, according to Rice.

“With the surge in battery use, particularly in EVs, the need for developing sustainable recycling methods is pressing,” Tour said in a statement.

Similar to the REM process, this technique known as flash Joule heating (FJH) heats waste to 2,500 Kelvin within seconds, which allows for efficient purification through magnetic separation.

This research was also supported by the U.S. Army Corps of Engineers, as well as the Air Force Office of Scientific Research and Rice Academy Fellowship.

Last year, a fellow Rice research team earned a grant related to soil in the energy transition. Mark Torres, an assistant professor of Earth, environmental and planetary sciences; and Evan Ramos, a postdoctoral fellow in the Torres lab; were given a three-year grant from the Department of Energy to investigate the processes that allow soil to store roughly three times as much carbon as organic matter compared to Earth's atmosphere.

By analyzing samples from the East River Watershed, the team aims to understand if "Earth’s natural mechanisms of sequestering carbon to combat climate change," Torres said in a statement.

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This article originally ran on InnovationMap.

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Prominent Houston energy business leader to retire, successor named

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A Texas wind energy project has officially delivered and is actively providing power to its customer, Target Corp.

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The rig stands 225 feet tall and extends 8,000 feet below the subsurface. Photo via exxonmobil.com

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New study from Houston research team looks at how the Earth cycles fossil carbon

A Rice University professor studied the Earth's carbon cycle in the Rio Madre de Dios to shed light on current climate conditions. Photo courtesy of Mark Torres/Rice University

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A Rice University professor studied the Earth's carbon cycle in the Rio Madre de Dios to shed light on current climate conditions. Photo courtesy of Mark Torres/Rice University

New study from Houston research team looks at how the Earth cycles fossil carbon

analyzing earth

Carbon cycles through Earth, its inhabitants, and its atmosphere on a regular basis, but not much research has been done on that process and qualifying it — until now.

Torres published his findings in a study published in PNAS, explaining how they used rhenium — a silvery-gray, heavy transition metal — as a proxy for carbon. The research into the Earth’s natural, pre-anthropogenic carbon cycle stands to benefit humanity by providing valuable insight to current climate challenges.

“This research used a newly-developed technique pioneered by Robert Hilton and Mathieu Dellinger that relies on a trace element — rhenium — that’s incorporated in fossil organic matter,” Torres says. “As plankton die and sink to the bottom of the ocean, that dead carbon becomes chemically reactive in a way that adds rhenium to it.”

The research was done in the Rio Madre de Dios basin and supported by funding from a European Research Council Starting Grant, the European Union COFUND/Durham Junior Research Fellowship, and the National Science Foundation.

“I’m very excited about this tool,” Torres said. “Rice students have deployed this same method in our lab here, so now we can make this kind of measurement and apply it at other sites. In fact, as part of current research funded by the National Science Foundation, we are applying this technique in Southern California to learn how tectonics and climate influence the breakdown of fossil carbon.”

Torres also received a three-year grant from the Department of Energy to study soil for carbon storage earlier this year.

Two Rice University researchers just received DOE funding for carbon storage research. Photo by Gustavo Raskosky/Rice University

Research team lands DOE grant to investigate carbon storage in soil

planting climate change impact

Two researchers at Rice University are digging into how soil is formed with hopes to better understand carbon storage and potential new methods for combating climate change.

Backed by a three-year grant from the Department of Energy, the research is led by Mark Torres, an assistant professor of Earth, environmental and planetary sciences; and Evan Ramos, a postdoctoral fellow in the Torres lab. Co-investigators include professors and scientists with the Brown University, University of Massachusetts Amherst and Lawrence Berkeley National Laboratory.

According to a release from Rice, the team aims to investigate the processes that allow soil to store roughly three times as much carbon as organic matter compared to Earth's atmosphere.

“Maybe there’s a way to harness Earth’s natural mechanisms of sequestering carbon to combat climate change,” Torres said in a statement. “But to do that, we first have to understand how soils actually work.”

The team will analyze samples collected from different areas of the East River watershed in Colorado. Prior research has shown that rivers have been great resources for investigating chemical reactions that have taken place as soil is formed. Additionally, research supports that "clay plays a role in storing carbon derived from organic sources," according to Rice.

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Additionally, the researchers plan to create a model that better quantifies the stabilization of organic carbon over time. According to Torres, the model could provide a basis for predicting carbon dioxide changes in Earth's atmosphere.

"We’re trying to understand what keeps carbon in soils, so we can get better at factoring in their role in climate models and render predictions of carbon dioxide changes in the atmosphere more detailed and accurate,” Torres explained in the statement.

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Major Houston energy companies join new Carbon Measures coalition

green team

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Houston-area members of the Carbon Measures coalition are:

Spring-based ExxonMobil
Air Liquide, whose U.S. headquarters is in Houston
Mitsubishi Heavy Industries, whose U.S. headquarters is in Houston
Honeywell, whose Performance Materials and Technologies business is based in Houston.
BASF, whose global oilfield solutions business is based in Houston
Linde, whose Linde Engineering Americas business is based in Houston

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nuclear pilot

The Texas A&M University System and Last Energy plan to launch a micro-nuclear reactor pilot project next summer at the Texas A&M-RELLIS technology and innovation campus in Bryan.

Washington, D.C.-based Last Energy will build a 5-megawatt reactor that’s a scaled-down version of its 20-megawatt reactor. The micro-reactor initially will aim to demonstrate safety and stability, and test the ability to generate electricity for the grid.

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Glenn Hegar, chancellor of the Texas A&M system, said the 5-megawatt reactor is the kind of project the system had in mind when it built the 2,400-acre Texas A&M-RELLIS campus.

The project is “bold, it’s forward-looking, and it brings together private innovation and public research to solve today’s energy challenges,” Hegar said.

As it gears up to build the reactor, Last Energy has secured a land lease at Texas A&M-RELLIS, obtained uranium fuel, and signed an agreement with DOE. Founder and CEO Bret Kugelmass said the project will usher in “the next atomic era.”

In February, John Sharp, chancellor of Texas A&M’s flagship campus, said the university had offered land at Texas A&M-RELLIS to four companies to build small modular nuclear reactors. Power generated by reactors at Texas A&M-RELLIS may someday be supplied to the Electric Reliability Council of Texas (ERCOT) grid.

Also in February, Last Energy announced plans to develop 30 micro-nuclear reactors at a 200-acre site about halfway between Lubbock and Fort Worth.

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