fresh funding

Houston-led research team granted $4.1M for carbon synthesis project, calls for collaboration

A Rice University team researching carbon nanotube synthesis has received $4.1 million funding from both Rice’s Carbon Hub and The Kavli Foundation. Photo by Gustavo Raskosky/Rice University

A Rice University-led team of scientists has been awarded a $4.1 million grant to optimize a synthesis process that could make carbon materials sustainable and affordable on a large scale.

Known as carbon nanotube (CNT) synthesis, the process has the ability to create hollow cylindrical nanoscale structures made from carbon atoms that are strong, lightweight and carry heat and electricity well. CNT synthesis evolved across multiple countries around the same time, according to Rice. But to scale up the process in a way that could create alternatives to materials dependent on heavy industry, Matteo Pasquali, the team's leader and the A.J. Hartsook Professor of Chemical and Biomolecular Engineering, says collaboration will be required.

“We have to apply a collaborative mindset to solve this problem,” Pasquali says in a statement. “We believe that by bringing together a dedicated interdisciplinary community, this project will lead to improvements in reactor efficiency and help identify further gaps in instrumentation and modeling.”

The grant seeks to achieve that. The funds come from both Rice’s Carbon Hub, which contributed $2.2 million to the team, and The Kavli Foundation, which granted $1.9 million in the form of a Kavli Exploration Award in Nanoscience for Sustainability.

The Kavli Foundation supports research in astrophysics, nanoscience, neuroscience and theoretical physics. Winners of its Kavli Prize, which recognizes scientific breakthroughs, often go on to win the Nobel Prize.

“We are proud to partner with Rice University to support this important high-risk, high-reward research,” says Amy Bernard, director of life sciences at The Kavli Foundation, says in a statement.

Pasquali is the director and one of the creators of Rice's Carbon Hub, a collaborative group of corporations, researchers, universities and nonprofits focused on decarbonizing the economy. He says the grant will help the team develop tools to shed light on CNT formation and reaction zones.

“We are at a critical juncture in carbon research, and it is really important that we shed light on the physical and chemical processes that drive CNT synthesis,” Pasquali says. “Currently, reactors are black boxes, which prevents us from ramping up synthesis efficiency. We need to better understand the forces at play in CNT formation by developing new tools to shed light on the reaction zone and find ways to leverage it to our advantage.”

Boris Yakobson, the Karl F. Hasselmann Professor of Engineering and professor of materials science and nanoengineering at Rice, and Thomas Senftle, assistant professor of chemical and biomolecular engineering at Rice, are also involved in the project. Other collaborators hail from the UK, Italy, Korea, and Spain, as well as U.S. labs and universities, including Harvard, Stanford, MIT and others.

In October, a separate team of Rice researchers released a study on a new synthesis process with applications in developing commercially relevant solar cells.

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A View From HETI

Rice University scientists' “recharge-to-recycle” reactor has major implications for the electric vehicle sector. Photo courtesy Jorge Vidal/Rice University.

Engineers at Rice University have developed a cleaner, innovative process to turn end-of-life lithium-ion battery waste into new lithium feedstock.

The findings, recently published in the journal Joule, demonstrate how the team’s new “recharge-to-recycle” reactor recharges the battery’s waste cathode materials to coax out lithium ions into water. The team was then able to form high-purity lithium hydroxide, which was clean enough to feed directly back into battery manufacturing.

The study has major implications for the electric vehicle sector, which significantly contributes to the waste stream from end-of-life battery packs. Additionally, lithium tends to be expensive to mine and refine, and current recycling methods are energy- and chemical-intensive.

“Directly producing high-purity lithium hydroxide shortens the path back into new batteries,” Haotian Wang, associate professor of chemical and biomolecular engineering, co-corresponding author of the study and co-founder of Solidec, said in a news release. “That means fewer processing steps, lower waste and a more resilient supply chain.”

Sibani Lisa Biswal, chair of Rice’s Department of Chemical and Biomolecular Engineering and the William M. McCardell Professor in Chemical Engineering, also served as co-corresponding author on the study.

“We asked a basic question: If charging a battery pulls lithium out of a cathode, why not use that same reaction to recycle?” Biswal added in the release. “By pairing that chemistry with a compact electrochemical reactor, we can separate lithium cleanly and produce the exact salt manufacturers want.”

The new process also showed scalability, according to Rice. The engineers scaled the device to 20 square centimeters, then ran a 1,000-hour stability test and processed 57 grams of industrial black mass supplied by industry partner Houston-based TotalEnergies. The results produced lithium hydroxide that was more than 99 percent pure. It also maintained an average lithium recovery rate of nearly 90 percent over the 1,000-hour test, showing its durability. The process also worked across multiple battery chemistries, including lithium iron phosphate, lithium manganese oxide and nickel-manganese-cobalt variants.

Looking ahead, the team plans to scale the process and consider ways it can sustain high efficiency for greater lithium hydroxide concentrations.

“We’ve made lithium extraction cleaner and simpler,” Biswal added in the release. “Now we see the next bottleneck clearly. Tackle concentration, and you unlock even better sustainability.

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