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University of Houston selected for DOE-backed energy storage innovation initiative

The University of Houston has joined the Energy Storage Research Alliance, one of two DOE-backed energy innovation hubs. Photo via Getty Images

The University of Houston was selected for a new energy storage initiative from the United States Department of Energy.

UH is part of the Energy Storage Research Alliance (ESRA), which is one of the two energy innovation hubs that the DOE is creating with $125 million. The DOE will provide up to $62.5 million in ESRA funding over a span of five years.

“To fuel innovation and cultivate a sustainable and equitable energy future, all universities, government entities, industry and community partners have to work together,” Ramanan Krishnamoorti, vice president for energy and innovation at UH, says in a news release. “No one person or entity can achieve all this by themselves. As the Energy University and a Carnegie-designated Tier One research university, located in Houston — a center of diverse talent and experience from across the energy industry — UH has a unique advantage of continuing to build on Houston’s global leadership and demonstrating solutions at scale.

The hubs will attempt to address battery challenges and encourage next-generation innovation, which include safety, high-energy density and long-duration batteries. The batteries will be made from inexpensive, abundant materials, per the release.

The work that will be done at ESRA and other hubs can optimize renewable energy usage, reduce emissions, enhance grid reliability, and assist in growing electric transportation, and other clean energy solutions.

ESRA will bring in 50 researchers from three national laboratories and 12 other universities, including UH. The deputy lead of the soft matter scientific thrust and the principal investigator for UH’s portion of the project will be Yan Yao. Yao is the Hugh Roy and Lillie Cranz Cullen Distinguished Professor at the UH Cullen College of Engineering and principal investigator at the Texas Center for Superconductivity.

UH professor Yan Yao will lead the school's participation in the program. Photo via UH.edu

ESRA will focus on three interconnected scientific thrusts and how they work together: liquids, soft matter, and condensed matter phases. Yao and his team have created next-generation batteries using low-cost organic materials. The team previously used quinones that can be synthesized from plants and food like soybeans to increase energy density, electrochemical stability and safety in the cathode. Yao’s team were the first to make solid-state sodium batteries by using multi-electron conformal organic cathodes. The cathodes had a demonstrated record of recharging stability of 500 charging cycles.

Robert A. Welch Assistant Professor of electrical and computer engineering at UH Pieremanuele Canepa, will serve as co-PI. Both will investigate phase transitions in multi-electron redox materials and conformable cathodes to enable solid-state batteries by “marrying Yao’s experimental lab work with Canepa’s expertise in computational material science,” according to the release.

Joe Powell, founding director of the UH Energy Transition Institute and a professor in the Department of Chemical and Biomolecular Engineering, will create a community benefit plan and develop an energy equity course.

“New energy infrastructure and systems can have benefits and burdens for communities,” Powell says in the release. “Understanding potential issues and partnering to develop best solutions is critical. We want everyone to be able to participate in the new energy economy and benefit from clean energy solutions.”

This project will be led by Argonne National Laboratory and co-led by Lawrence Berkeley National Laboratory and Pacific Northwest National Laboratory.

“This is a once in a lifetime opportunity,” adds Yao. “To collaborate with world-class experts to understand and develop new science and make discoveries that will lead to the next generation of batteries and energy storage concepts, and potentially game changing devices is exciting. It’s also a great opportunity for our students to learn from and work with top scientists in the country and be part of cutting-edge research.”

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A View From HETI

Rice University scientists' “recharge-to-recycle” reactor has major implications for the electric vehicle sector. Photo courtesy Jorge Vidal/Rice University.

Engineers at Rice University have developed a cleaner, innovative process to turn end-of-life lithium-ion battery waste into new lithium feedstock.

The findings, recently published in the journal Joule, demonstrate how the team’s new “recharge-to-recycle” reactor recharges the battery’s waste cathode materials to coax out lithium ions into water. The team was then able to form high-purity lithium hydroxide, which was clean enough to feed directly back into battery manufacturing.

The study has major implications for the electric vehicle sector, which significantly contributes to the waste stream from end-of-life battery packs. Additionally, lithium tends to be expensive to mine and refine, and current recycling methods are energy- and chemical-intensive.

“Directly producing high-purity lithium hydroxide shortens the path back into new batteries,” Haotian Wang, associate professor of chemical and biomolecular engineering, co-corresponding author of the study and co-founder of Solidec, said in a news release. “That means fewer processing steps, lower waste and a more resilient supply chain.”

Sibani Lisa Biswal, chair of Rice’s Department of Chemical and Biomolecular Engineering and the William M. McCardell Professor in Chemical Engineering, also served as co-corresponding author on the study.

“We asked a basic question: If charging a battery pulls lithium out of a cathode, why not use that same reaction to recycle?” Biswal added in the release. “By pairing that chemistry with a compact electrochemical reactor, we can separate lithium cleanly and produce the exact salt manufacturers want.”

The new process also showed scalability, according to Rice. The engineers scaled the device to 20 square centimeters, then ran a 1,000-hour stability test and processed 57 grams of industrial black mass supplied by industry partner Houston-based TotalEnergies. The results produced lithium hydroxide that was more than 99 percent pure. It also maintained an average lithium recovery rate of nearly 90 percent over the 1,000-hour test, showing its durability. The process also worked across multiple battery chemistries, including lithium iron phosphate, lithium manganese oxide and nickel-manganese-cobalt variants.

Looking ahead, the team plans to scale the process and consider ways it can sustain high efficiency for greater lithium hydroxide concentrations.

“We’ve made lithium extraction cleaner and simpler,” Biswal added in the release. “Now we see the next bottleneck clearly. Tackle concentration, and you unlock even better sustainability.

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