seeing green

Houston team researching how algae can combat climate change

Venkatesh Balan and his team at UH are researching ways fresh- and salt-water phototropic organisms, or microalge, can sequester carbon from industrial refineries and convert it into useful byproducts. Photo via UH.edu

Researchers at the University of Houston are looking at an alternative way to capture carbon that uses a surprising conduit: algae.

In a newly published article in Green Chemistry, a journal of the Royal Society of Chemistry, Venkatesh Balan, associate professor of engineering technology at UH, details how he and his team are researching ways fresh- and salt-water phototropic organisms, or microalgae, can sequester carbon from industrial refineries and convert it into useful byproducts.

Balan is joined by UH researchers James Pierson and Hasan Husain, Sandeep Kimar from Old Dominion University, Christopher Saffron of Michigan State University, and Vinod Kumar from Cranfield University in the United Kingdom.

According to a release from UH, Balan and research assistant Masha Alian have uncovered how microalgae can produce fungus like lichen and create healthy food products. After microalge captures the carbon, it then converts that CO2 into mass-produced proteins, lipids and carbohydrates, according to the team's research.

“We are coming up with the alternate approach of using algae to fix the CO2 then using the carbon to make bioproducts that are useful to mankind,” Balan said in the release.

The method offers an alternative to other carbon capture options that aim to burry carbon, which is expensive and energy intensive, according to UH.

Balan says this research also has applications in wastewater treatment and the production of food, fertilizers, fuels and chemicals, all of which could lessen the dependency on fossil fuels in the future.

"On your table or in your pantry, you see food products. What’s harder to visualize are the greenhouse gasses emitted by the orchard that grows the fruit, the factory that makes the breakfast cereal, the transportation that brings the cookies to your neighborhood, even your own commute to buy the food," Balan said. "It adds up, but the problem is easy to ignore because we can’t see it. Yet all consumers contribute, in our own way, to the greenhouse effect.”

The UH team is just one of many Houston groups looking at unconventional, although natural ways to combat climate change.

In September, Rice University announced that two researchers were awarded a three-year grant from the Department of Energy for their research into the processes that allow soil to store roughly three times as much carbon as organic matter compared to Earth's atmosphere.

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A View From HETI

Rice University scientists' “recharge-to-recycle” reactor has major implications for the electric vehicle sector. Photo courtesy Jorge Vidal/Rice University.

Engineers at Rice University have developed a cleaner, innovative process to turn end-of-life lithium-ion battery waste into new lithium feedstock.

The findings, recently published in the journal Joule, demonstrate how the team’s new “recharge-to-recycle” reactor recharges the battery’s waste cathode materials to coax out lithium ions into water. The team was then able to form high-purity lithium hydroxide, which was clean enough to feed directly back into battery manufacturing.

The study has major implications for the electric vehicle sector, which significantly contributes to the waste stream from end-of-life battery packs. Additionally, lithium tends to be expensive to mine and refine, and current recycling methods are energy- and chemical-intensive.

“Directly producing high-purity lithium hydroxide shortens the path back into new batteries,” Haotian Wang, associate professor of chemical and biomolecular engineering, co-corresponding author of the study and co-founder of Solidec, said in a news release. “That means fewer processing steps, lower waste and a more resilient supply chain.”

Sibani Lisa Biswal, chair of Rice’s Department of Chemical and Biomolecular Engineering and the William M. McCardell Professor in Chemical Engineering, also served as co-corresponding author on the study.

“We asked a basic question: If charging a battery pulls lithium out of a cathode, why not use that same reaction to recycle?” Biswal added in the release. “By pairing that chemistry with a compact electrochemical reactor, we can separate lithium cleanly and produce the exact salt manufacturers want.”

The new process also showed scalability, according to Rice. The engineers scaled the device to 20 square centimeters, then ran a 1,000-hour stability test and processed 57 grams of industrial black mass supplied by industry partner Houston-based TotalEnergies. The results produced lithium hydroxide that was more than 99 percent pure. It also maintained an average lithium recovery rate of nearly 90 percent over the 1,000-hour test, showing its durability. The process also worked across multiple battery chemistries, including lithium iron phosphate, lithium manganese oxide and nickel-manganese-cobalt variants.

Looking ahead, the team plans to scale the process and consider ways it can sustain high efficiency for greater lithium hydroxide concentrations.

“We’ve made lithium extraction cleaner and simpler,” Biswal added in the release. “Now we see the next bottleneck clearly. Tackle concentration, and you unlock even better sustainability.

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