it's a deal

ExxonMobil enters into off-take agreement with EV battery manufacturer

The off-take agreement will provide SK On with ExxonMobil's lithium produced in Arkansas. Photo via exxonmobil.com

ExxonMobil has signed a non-binding memorandum of understanding with South Korean electric vehicle battery developer SK On.

The deal aims to secure a multiyear off-take agreement of up to 100,000 metric tons of MobilTM Lithium from the company’s first planned project in Arkansas. SK On will use the lithium in its EV battery manufacturing operations in the United States, which will contribute to ExxonMobil’s 2023 goal of supplying lithium for nearly 1 million EV batteries annually by 2030, and also assist in the build out of a U.S. EV supply chain.

The Arkansas project proposes an extraction of lithium from underground saltwater deposits and converting it into battery-grade material onsite. The approach will produce lithium more efficiently and with fewer environmental impacts than traditional hard rock mining, according to ExxonMobil. Consumer electronics, energy storage systems, and other clean energy technologies have all shown increased use in lithium needs.

The planned production of MobilTM Lithium will use ExxonMobil's core capabilities in drilling, subsurface exploration, and chemical processing, which should offer U.S. EV battery manufacturers a lower-carbon lithium supply option.

“The world needs more lithium to support its emissions goals, and we're doing our part to drive solutions forward in the United States,” Dan Ammann, president of ExxonMobil Low Carbon Solutions, says in a news release. “This collaboration with SK On demonstrates the leading role we play in the growing market for domestically sourced lithium, a market that’s advancing energy security and climate objectives, as well as supporting American manufacturing."

The annual production capacity of SK On in the U.S. alone is expected to reach more than 180 GWh in 2025. That production is enough to power around 1.7 million EVs per year.

“Through this partnership with ExxonMobil, we will continue strengthening battery supply chains in the U.S.,” Park Jong-jin, executive vice president of Strategic Procurement at SK On, adds.

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A View From HETI

Ahmad Elgazzar, Haotian Wang and Shaoyun Hao were members of a Rice University team that recently published findings on how acid bubbling can improve CO2 reduction systems. Photo courtesy Rice.

In a new study published in the journal Science, a team of Rice University researchers shared findings on how acid bubbles can improve the stability of electrochemical devices that convert carbon dioxide into useful fuels and chemicals.

The team led by Rice associate professor Hoatian Wang addressed an issue in the performance and stability of CO2 reduction systems. The gas flow channels in the systems often clog due to salt buildup, reducing efficiency and causing the devices to fail prematurely after about 80 hours of operation.

“Salt precipitation blocks CO2 transport and floods the gas diffusion electrode, which leads to performance failure,” Wang said in a news release. “This typically happens within a few hundred hours, which is far from commercial viability.”

By using an acid-humidified CO2 technique, the team was able to extend the operational life of a CO2 reduction system more than 50-fold, demonstrating more than 4,500 hours of stable operation in a scaled-up reactor.

The Rice team made a simple swap with a significant impact. Instead of using water to humidify the CO2 gas input into the reactor, the team bubbled the gas through an acid solution such as hydrochloric, formic or acetic acid. This process made more soluble salt formations that did not crystallize or block the channels.

The process has major implications for an emerging green technology known as electrochemical CO2 reduction, or CO2RR, that transforms climate-warming CO2 into products like carbon monoxide, ethylene, or alcohols. The products can be further refined into fuels or feedstocks.

“Using the traditional method of water-humidified CO2 could lead to salt formation in the cathode gas flow channels,” Shaoyun Hao, postdoctoral research associate in chemical and biomolecular engineering at Rice and co-first author, explained in the news release. “We hypothesized — and confirmed — that acid vapor could dissolve the salt and convert the low solubility KHCO3 into salt with higher solubility, thus shifting the solubility balance just enough to avoid clogging without affecting catalyst performance.”

The Rice team believes the work can lead to more scalable CO2 electrolyzers, which is vital if the technology is to be deployed at industrial scales as part of carbon capture and utilization strategies. Since the approach itself is relatively simple, it could lead to a more cost-effective and efficient solution. It also worked well with multiple catalyst types, including zinc oxide, copper oxide and bismuth oxide, which are allo used to target different CO2RR products.

“Our method addresses a long-standing obstacle with a low-cost, easily implementable solution,” Ahmad Elgazzar, co-first author and graduate student in chemical and biomolecular engineering at Rice, added in the release. “It’s a step toward making carbon utilization technologies more commercially viable and more sustainable.”

A team led by Wang and in collaboration with researchers from the University of Houston also shared findings on salt precipitation buildup and CO2RR in a recent edition of the journal Nature Energy. Read more here.

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