power deal

Exxon expands CO2 storage network with Calpine agreement

ExxonMobil has agreed to transport CO2 from Calpine Corp.’s Baytown Energy Center. Photo via Getty Images.

ExxonMobil Corp. has agreed to transport and permanently store up to 2 million metric tons per year of CO2 from Calpine Corp.’s Baytown Energy Center.

The strategic agreement is part of Calpine’s Baytown Carbon Capture and Storage (CCS) Project, which is designed to capture the energy center’s CO2 emissions and enable the supply of low-carbon electricity. It’s also in line with Exxon’s broader strategy to expand its CCS infrastructure along the Gulf Coast.

“Calpine is excited to partner with ExxonMobil to achieve this important project milestone,” Caleb Stephenson, Calpine Executive Vice President, said in a news release. “As the largest U.S. generator of electricity from natural gas, we understand that the nation’s gas fleet will remain the backbone of the grid for decades to come. We believe CCS is an actionable and cost-effective way to meet customers' demand for reliable power and alleviate concerns about the indisputable long-term need for gas-fired facilities. Low-cost natural gas along with carbon capture technology and widespread geologic storage resources can bolster U.S. energy, natural gas use, jobs, and export strength.”

The Baytown CCS Project is expected to produce about 500 megawatts of low-carbon electricity, which Calpine said is enough to power more than 500,000 homes. It can also provide steam for nearby industrial purposes.

The project anticipates creating construction and other full-time jobs, with engineering, permitting, and other development activities coming soon.

"We’re thrilled to work with Calpine on this project that supports American energy security, enhances industrial competitiveness and leverages America’s abundant low-cost natural gas resources," Barry Engle, President of ExxonMobil Low Carbon Solutions, said in a news release. “This agreement underscores the growing confidence our customers across diverse sectors—including steel, fertilizer, industrial gases, natural gas processing, and now power generation—have in our unique end-to-end CCS system.”

This is ExxonMobil’s sixth CCS customer, bringing the company's total amount of CO2 under contract to approximately 16 million tons a year, according to the company. The CO2 from Calpine’s facility will tie into ExxonMobil’s CO2 pipeline system on the Gulf Coast.

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A View From HETI

The world is trending toward producing 82 million metric tons of flame-retardant plastic waste by 2030. Photo via Unsplash

Researchers at Rice University have developed a new technique to efficiently recycle electronic waste and harvest critical minerals using rapid heating.

Most electronic devices use flame-retardant plastic. The plastic is formulated from a critical metal called antimony.

However, recapturing antimony is typically a challenging task since it first has to be released from the plastic. As it is released, other compounds can form, such as organic bromides, which are toxic and difficult to capture. However, the organic bromides can also be reused and have applications in industrial chemicals when safely captured.

“Conventionally heating the plastic releases the antimony in a volatile and difficult-to-collect form as well as creating and releasing hazardous organic bromide compounds,” Leo Haoxin Ye, first author of the paper and a graduate student at Rice, said in a news release. “Other options are risky or more impractical, such as using strong acids, organic solvents or multistep treatment options.”

To address this issue, leading Rice chemistry professor James Tour, Ye and their team adapted Tour’s flash Joule heating technique, which heats materials to hundreds of degrees Celsius in milliseconds, according to Rice.

The team ground up flame-retardant plastic waste and placed it between two sheets of electrically heated carbon paper before using what’s known as isothermal-clamped flash Joule heating to release and collect the antimony.

The team found that limiting the time the plastic spent in the high temperature range dramatically reduced the production of the hazardous organic bromide compounds. The plastic remained between 200 degrees and 500 degrees Celsius for only 9.4 milliseconds, according to Rice.

Through the process, the team recovered 90 percent of antimony from tested materials and converted 83 percent of the bromide into hydrogen bromide. Their findings were published this month in the journal Nature Chemical Engineering.

“Isothermal-clamped flash Joule heating could improve the speed, safety and practicality of antimony recovery from discarded flame-retardant plastics,” Tour added in the release. “This represents an important step forward to conserving and reusing our critical antimony supply while also regenerating bromide salts for reuse.”

The study noted that the world is currently trending toward producing 82 million metric tons of flame-retardant plastic waste by 2030, which adds to the fact that e-waste is the fastest-growing solid waste stream in the world.

The research was funded by the Air Force Office of Scientific Research and the U.S. Army Corps of Engineers.

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