Houston researchers develop catalyst for emission-free hydrogen production using light instead of heat

switch flipped

Researchers created a light-driven catalyst for hydrogen production, offering an emission-free alternative to traditional methods. Photo by Jeff Fitlow/Rice University

Researchers at Rice University have developed a catalyst that could render steam methane reforming, or SMR, entirely emission-free by using light rather than heat to drive the reaction.

The researchers believe the work could prove to be a breakthrough for extending catalyst lifetimes. This will improve efficiencies and reduce costs for a number of industrial processes that are affected by a form of carbon buildup that can deactivate catalysts called coking.

The new copper-rhodium photocatalyst uses an antenna-reactor design. When it is exposed to a specific wavelength of light it breaks down methane and water vapor without external heating into hydrogen and carbon monoxide. The importance of this is it is a chemical industry feedstock that is not a greenhouse gas. Rice’s work also shows that the antenna-reactor technology can overcome catalyst deactivation due to oxidation and coking by employing hot carriers to remove oxygen species and carbon deposits, which effectively regenerates the catalyst with light.

The new SMR reaction pathway build off a 2011 discovery from Peter Nordlander, Rice’s Wiess Chair and Professor of Physics and Astronomy and professor of electrical and computer engineering and materials science and nanoengineering, and Naomi Halas. They are the authors on the study about the research that was published in Nature Catalysis. The study showed that the collective oscillations of electrons that occur when metal nanoparticles are exposed to light can emit “hot carriers” or high-energy electrons and holes that can be used to drive chemical reactions.

“This is one of our most impactful findings so far, because it offers an improved alternative to what is arguably the most important chemical reaction for modern society,” Norlander says in a news release.

The research was supported by Robert A. Welch Foundation (C-1220, C-1222) and the Air Force Office of Scientific Research (FA9550-15-1-0022) with the Shared Equipment Authority at Rice providing data analysis support.

“This research showcases the potential for innovative photochemistry to reshape critical industrial processes, moving us closer to an environmentally sustainable energy future,” Halas adds.

Hydrogen has been studied as it could assist with the transition to a sustainable energy ecosystem, but the chemical process responsible for more than half of the current global hydrogen production is a substantial source of greenhouse gas emissions.Hydrogen is produced in large facilities that require the gas to be transported to its point of use. Light-driven SMR allows for on-demand hydrogen generation,which researchers believe is a key benefit for use in mobility-related applications like hydrogen fueling stations or and possibly vehicles.

Rice University will open a hub in Bengaluru, India, to focus on sustainable energy, AI, biotechnology, and global research collaboration. Photo via Rice University

Houston university launches global hub to drive innovation in sustainable energy, advanced technologies

incoming, India

Rice University is launching Rice Global India, which is a strategic initiative to expand India’s rapidly growing education and technology sectors.

The new hub will be in the country’s third-largest city and the center of the country’s high-tech industry, Bengaluru, India, and will include collaborations with top-tier research and academic institutions. Rice continues its collaborations with institutions like the Indian Institute of Technology (IIT) Kanpur and the Indian Institute of Science (IISc) Bengaluru. The partnerships are expected to advance research initiatives, student and faculty exchanges and collaborations in artificial intelligence, biotechnology and sustainable energy.

“India is a country of tremendous opportunity, one where we see the potential to make a meaningful impact through collaboration in research, innovation and education,” Rice President Reginald DesRoches says in a news release. “Our presence in India is a critical step in expanding our global reach, and we are excited to engage more with India’s academic leaders and industries to address some of the most pressing challenges of our time.”

India was a prime spot for the location due to the energy, climate change, artificial intelligence and biotechnology studies that align with Rice’s research that is outlined in its strategic plan Momentous: Personalized Scale for Global Impact.

“India’s position as one of the world’s fastest-growing education and technology markets makes it a crucial partner for Rice’s global vision,” vice president for global at Rice Caroline Levander adds. “The U.S.-India relationship, underscored by initiatives like the U.S.-India Initiative on Critical and Emerging Technology, provides fertile ground for educational, technological and research exchanges.”

On November 18, the university hosted a ribbon-cutting ceremony in Bengaluru, India to help launch the project.

“This expansion reflects our commitment to fostering a more interconnected world where education and research transcend borders,” DesRoches says.

———

This article originally ran on InnovationMap.

Energy Tech Nexus has opened in downtown Houston. Photo by Natalie Harms/EnergyCapital

Houston leaders launch new downtown hub to support energy transition innovation

ribbon cutting

Three Houston energy innovators have cut the ribbon on a new space for energy transition innovation.

The Energy Tech Nexus, located in the historic Niels Esperson Building at the corner of Travis and Rusk Avenue, opened on September 10, which was proclaimed Energy Tech Nexus Day by the city.

Jason Ethier and Juliana Garaizar, formerly in leadership roles at Greentown Labs, teamed up with Nada Ahmed, previously headed innovation and transformation at Aker Solutions, launched ETN as a community for energy transition startups. The new hub plans to host incubation programs, provide mentorship, and open doors to funding and strategic partnerships for its members.

"We are creating more than a space for innovation," Garaizar says in a news release. "We are crafting a community where pioneers in technology and energy converge to challenge the status quo and accelerate the shift to sustainable energy solutions."

The hub describes its goal of tackling the "trilemma" of energy security, sustainability, and affordability while also contributing to the mission of setting up Houston as the global center for energy transition. To accomplish that mission, ETN will help facilitate rapid deployment of cutting-edge energy technologies.

'The future of energy is not just being written here in Houston; it's being rewritten in more sustainable, efficient, and innovative ways," adds Garaizar. "Houston provides the perfect backdrop for this transformation, offering a rich history in energy and a forward-looking approach to its challenges and opportunities."

"We believe that a broad spectrum of perspectives is crucial in solving global energy challenges. It's about bringing everyone to the table — startups, industry leaders, and investors from all backgrounds," she continues.

Ethier, who co-hosts the Energy Tech Startups Podcast with Ahmed, says he hopes that ETN acts as a meeting place for energy transition innovators.

"By providing the right tools, access, and expertise, we are enabling these companies to leap from ideation to implementation at an unprecedented pace;" Ethier explains. "The interaction between startups and established companies within Energy Tech Nexus creates a unique synergy, fostering innovations that might otherwise take years to mature in isolation."

Payal Patel, an angel investor who has held leadership roles at Station Houston, Plug and Play Ventures, and Softeq, also contributed to launching ETN, which is collaborating with George Liu, who has over 15 years of investment banking experience across energy, cleantech and hardtech with more than $20 billion in M&A projects across his career.

In May, ETN teamed up with Impact Hub Houston to establish the Equitable Energy Transition Alliance and Lab to accelerate startup pilots for underserved communities. The initiative announced that it's won the 2024 U.S. Small Business Administration Growth Accelerator Fund Competition, or GAFC, Stage One award.

ETN celebrated its opening during the inaugural Houston Energy and Climate Week.

Debalina Sengupta has been named as the chief operating officer of UH's Energy Transition Institute. Photo via UH.edu

University of Houston names new energy transition-focused executive

leading the way

The University of Houston has named a new C-level executive to its energy transition-focused initiative.

Debalina Sengupta has been named as the chief operating officer of UH's Energy Transition Institute, which was established in 2022 by a $10 million commitment from Shell USA Inc. and Shell Global Solutions (US) Inc. The institute focuses on hydrogen, carbon management and circular plastics and works closely with UH’s Hewlett Packard Enterprise Data Science Institute and researchers across the university.

Sengupta, who was previously a chemical engineer with over 18 years of experience with sustainability and resilience issues, was called to ETI’s mission and its focus on Houston, which is home to more than 4,500 energy companies and a pivotal international oil and gas hub.

“UH Energy Transition Institute is the first of its kind Institute setup in Texas that focuses solely on the transition of energy,” she says in a news release. “A two-way communication between the academic community and various stakeholders is necessary to implement the transition and I saw the UH ETI role enabling me to achieve this critical goal.”

Originally from India, where she saw first-hand the impact of natural disasters, she has been working with Texas coastal communities over the past two years to not help bring coastal resilience projects along the coast. The Texas coast will serve potentially as an economic development zone for several energy transition projects.

“It is necessary that we think deeply about sustainability quantification for our energy systems, diversify and expand from fossil to non-fossil resources, and understand how it can impact our future generations,” Sengupta continues. “This requires rigorous training and adopting new technologies that will enable the change, and I am dedicated to work towards this goal for UH ETI.”

Sengupta has also worked as a postdoctoral research fellow in the U.S. Environmental Protection Agency. She has a bachelor’s degree in chemical engineering from Jadavpur University in India and a doctorate from Louisiana State University with a focus on process systems engineering. Sengupta previously was at Texas A&M University where she was the Coastal Resilience Program director for Texas Sea Grant,which is a federal-state partnership program funded by the U.S. Department of Commerce National Oceanic and Atmospheric Administration. She has served as the associate director of the Texas A&M Engineering Experiment Station’s Gas and Fuels Research Center; coordinator of the Water, Energy and Food Nexus at Texas A&M Energy Institute; and lecturer at the Artie McFerrin Department of Chemical Engineering.

The ETI has helped catalyze “cross-disciplinary cooperation” to expand funding opportunities for UH faculty, which includes direct funding of over 24 projects via seed grants. As the new COO, Sengupta will work alongside founding executive director of the institute, Joe Powell, their executive team and the ETI advisory board to develop and implement strategic plans. Her position is partially funded by a $500,000 grant from the Houston-based Cullen Foundation.

“We are excited to have Dr. Sengupta join us at UH to help drive the Energy Transition Institute to fulfill its mission in educating students, expanding top-tier research, and providing thought leadership in sustainable energy and chemicals for the Houston area and beyond,” Powell adds. “Dr. Sengupta brings a strong background and network in collaborating with academic, community, governmental and industry partners to build the coalitions needed for success.”

The PhD and doctoral students will each receive a one-year $12,000 fellowship, along with mentoring from experts at UH and Chevron. Photo via UH.edu

University of Houston names first group of Chevron-backed fellows

meet the chosen ones

The University of Houston has named eight graduate students to its first-ever cohort of UH-Chevron Energy Graduate Fellows.

The PhD and doctoral students will each receive a one-year $12,000 fellowship, along with mentoring from experts at UH and Chevron. Their work focuses on energy-related research in fields ranging from public policy to geophysics and math. The fellowship is funded by Chevron.

“The UH-Chevron Energy Fellowship program is an exciting opportunity for our graduate students to research the many critical areas that impact the energy industry, our communities and our global competitiveness,” Ramanan Krishnamoortil UH's Vice President for Energy and Innovation says in a statement.

“Today’s students not only recognize the importance of energy, but they are actively driving the push for affordable, reliable, sustainable and secure energy and making choices that clearly indicate that they are meaningfully contributing to the change,” he continues.

“We love that Chevron is sponsoring this group of fellows because it’s a fantastic way for us to get involved with the students who are working on some of the biggest problems we’ll face in society,” Chevron Technology Ventures President Jim Gable adds.

The 2023 UH-Chevron Energy Graduate Fellows are:

Kripa Adhikari, a Ph.D. student in the Department of Civil and Environmental Engineering in the Cullen College of Engineering. Her work focuses on thermal regulation in enhanced geothermal systems. She currently works under the mentorship of Professor Kalyana Babu Nakshatrala and previously worked as a civil engineer with the Nepal Reconstruction Authority.

Aparajita Datta, a researcher at UH Energy and a Ph.D. candidate in the Department of Political Science. Her work focuses on the federal Low-Income Home Energy Assistance Program (LIHEAP), a redistributive welfare policy designed to help households pay their energy bills. She holds a bachelor’s degree in computer science and engineering from the University of Petroleum and Energy Studies in India, and master’s degrees in energy management and public policy from UH. She also recently worked on a paper for UH about transportation emissions.

Chirag Goel, a Ph.D. student in materials science and engineering at UH. His work focuses on using High Temperature Superconductors (HTS) to optimize manufacturing processes, which he says can help achieve carbon-free economies by 2050. The work has uses in renewable energy generation, electric power transmission and advanced scientific applications.

Meghana Idamakanti, a third-year Ph.D. student in the William A. Brookshire Department of Chemical and Biomolecular Engineering. Her work focuses on using electrically heated steam methane for cleaner hydrogen production. She received her bachelor’s degree in chemical engineering from Jawaharlal Nehru Technological University in India in 2020 and previously worked as a process engineering intern at Glochem Industries in India.

Erin Picton, an environmental engineering Ph.D. student in the Shaffer Lab at UH. Her work focuses on ways to increase the sustainability of lithium processing and reducing wasted water and energy. “I love the idea of taking waste and turning it into value,” she said in a statement. She has previously worked in collaboration with MIT and Greentown Labs, as chief sustainability officer of a Houston-based desalination startup; and as a visiting graduate researcher at Argonne National Lab and at INSA in Lyon, France.

Mohamad Sarhan, a Ph.D. student and a teaching assistant in the Department of Petroleum Engineering. His work focuses on seasonal hydrogen storage and the stability of storage candidates during hydrogen cycling. He holds a bachelor’s degree and a master’s degree in petroleum engineering from Cairo University

Swapnil Sharma, a Ph.D. student in the William A. Brookshire Department of Chemical and Biomolecular Engineering. His work has been funded by the Department of Energy and focuses on thermal modeling of large-scale liquid hydrogen storage tanks. He works with Professor Vemuri Balakotaiah. He holds bachelor's and master’s degrees in chemical engineering from the Indian Institute of Technology (IIT). He also developed one of the world’s highest fiber-count optical fiber cables while working in India and founded CovRelief, which helped millions of Indians find resources about hospital beds, oxygen suppliers and more during the pandemic.

Larkin Spires, who's working on her doctoral research in the Department of Earth and Atmospheric Sciences in the College of Natural Sciences and Mathematics. Her work focuses on a semi-empirical Brown and Korringa model for fluid substitution and the ties between geophysics and mathematics. She works under Professor John Castagna and holds a bachelor’s degree in math from Louisiana State University and a master’s degree in geophysics from UH.

Earlier this month Evolve Houston also announced its first-ever cohort of 13 microgrant recipients, whose work aims to make EVs and charging infrastructure more accessible in some of the city's more underserved neighborhoods.

The Houston Energy Transition Initiative spoke with Ramanan Krishnamoorti about the future of energy. Image via htxenergytransition.org

Empowering the next generation: Q&A with Ramanan Krishnamoorti

THE VIEW FROM HETI

College students stand at the intersection of youth climate activism and emerging academic research that has the power to reshape the future of energy. Dr. Ramanan Krishnamoorti believe that college students have the power to tackle some of the world’s most pressing issues in energy, if given the opportunity. Krishnamoorti serves as University of Houston Vice President for Energy and Innovation and professor of chemical and biomolecular engineering is leading the university’s efforts to establish education, research and outreach partnerships to address energy and innovation challenges.

HETI sat down with Dr. Krishnamoorti to learn more about his journey in the energy industry, the importance of engaging the youth in climate change and how community partners can give college students a seat at the energy transition table.

Q: You have a passionate way of speaking about the energy transition and the mission to get to net zero by 2050. Tell us about your background in the energy industry.

My journey in the energy industry began in academia as a chemical engineer, where my early scientific focus revolved around polymeric materials, which are closely tied to the industrial and societal applications of oil and gas beyond traditional fuels.

During the early 2000s, when our society faced an energy shortage and was grappling with pressing challenges, my interest in the broader energy landscape began to take shape. It was during that time that I assumed the role of chair of the Chemical Engineering Department at the University of Houston, which provided me the remarkable opportunity to establish the petroleum engineering program (eventually department), fostering close collaboration with industry stakeholders.

This experience granted me invaluable insights into the intricate operations of the energy industry as a whole, which ultimately led to me becoming the chief energy officer at UH. Over the past decade, my deep engagement across the energy industry has allowed me to fully grasp the immense value of energy and the critical challenges we face in ensuring that it remains affordable, reliable and sustainable.

Q: When it comes to the renewable energy workforce, you’ve spoken about the need to engage current K-12 students in STEM to ensure a robust talent pool in the future. What are some ways we can help students recognize their potential as change agents in the energy transition?

In today’s rapidly evolving energy landscape, success hinges on attracting a diverse and talented workforce, whether it be in the conventional oil and gas sector, the decarbonization realm (energy transition) or the renewable energy industry. Creating a broad and inclusive pathway that appeals to students from middle school onwards is crucial. We must vividly demonstrate the transformative power of their actions and the power of learning by doing. This would inspire them to explore the fundamental disciplines of science, technology, engineering and mathematics. By connecting these academic foundations to real world challenges, we can show them the immense impact they could have in shaping a sustainable and advancing future.

Energy is the lifeblood of modern society, and providing reliable, affordable and sustainable energy for all is our collective responsibility. We must convey to students the robust career opportunities available within the industry as a whole. The skills and knowledge gained in this field are highly transferable, enabling individuals to navigate various sectors and contribute to positive change across the entire energy spectrum but also help transform the world to one of opportunities for humanity.

Q: At the recent Future of Global Energy conference presented by Chevron, you spoke about the importance of empowering young leaders to act and influence decisions around energy, climate change and sustainability. How can leading energy companies give students and recent graduates a seat at the energy transition table?

Energy companies need to recognize the passion and impatience of this new generation and tap into it. These young individuals are eager to be part of the solution and are driven by a desire for tangible success in the challenge of building an equitable and sustainable energy sector. By providing opportunities for hands-on experience and learning-by-doing, energy companies can channel their enthusiasm and leverage their digital native mindset to develop scalable solutions for the grand challenge of energy solutions across the world.

Moreover, fostering a culture of mentorship and giving back is essential. Students and recent graduates have a strong inclination to make a positive societal impact. By offering organized mentorship programs within K-12 schools and higher education institutions, they can provide avenues for young talent to contribute meaningfully and gain valuable insights and guidance from industry professionals.

Lastly, it’s crucial for energy companies to recognize and embrace the inherent consideration of environmental, social and governance issues by the new generation of entrants. When confronted by complex engineering challenges, these young leaders naturally bring a constructive perspective that incorporates ESG considerations. By actively engaging with their perspectives, companies can benefit from fresh ideas and contribute to the overall advancement of sustainable practices.

Q: Do you believe that actions and initiatives put in place by young people have the power to trigger the momentum needed to help scale energy transition related businesses?

Absolutely! The energy transition demands innovative approaches to rapidly scale up technologies, while simultaneously addressing regulatory, financial and communication engagement challenges that may lag.

The new generation of students and industry entrants have demonstrated their ability to navigate bureaucratic systems that are two steps behind the problems they face, making them adept problem solvers. By empowering and supporting them, we can leverage their strengths to confront energy transition challenges head on. This team effort, combining their fresh perspectives with the necessary resources, will accelerate momentum and drive the scaling of energy transition-related businesses.

Q: Do students today recognize the importance of the energy transition?

Today’s students not only recognize the importance of the energy transition, but they are actively driving it and making choices that clearly indicate that they are meaningfully contributing to the change. They embrace risk-taking and innovative approaches to solve real-world energy challenges –– they are comfortable in a world where they understand the issue of bottlenecks (as is common in the complex energy systems) and the need for trade-offs.

What sets them apart is their dedication to promoting justice and equity. In fact, a recent poll conducted in collaboration with the UH Hobby School of Public Affairs revealed that many UH students prioritize companies committed to addressing societal and environmental issues, even if it means a sacrifice in salary. Their commitment speaks volumes about their desire to drive change.

Q: Looking toward the future of energy, how can universities and community partners provide support that fuels innovation and energy expertise in the youth today?

To fuel innovation and cultivate energy expertise in today’s youth, universities, industry leaders and community partners must collaborate. At the University of Houston, where approximately half of students are first-generation, it is our responsibility as educators to provide vital support. This includes facilitating connections, showcasing role models and expanding their awareness of opportunities. As the energy university located in Houston, a city rich in diverse talent, we have a unique advantage of continuing to build on Houston’s global leadership and demonstrating solutions at scale. By fostering this collaboration, we can inspire and empower the next generation.

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This article originally ran on the Greater Houston Partnership's Houston Energy Transition Initiative blog. HETI exists to support Houston's future as an energy leader. For more information about the Houston Energy Transition Initiative, EnergyCapitalHTX's presenting sponsor, visit htxenergytransition.org.

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Houston researchers earn $3.3M in DOE funding to develop safer underground power line installation

going under

Researchers from the University of Houston — along with a Hawaiian company — have received $3.3 million in funding to explore artificial intelligence-backed subsurface sensing system for safe and efficient underground power line installation.

Houston's power lines are above ground, but studies show underground power is more reliable. Installing underground power lines is costly and disruptive, but the U.S. Department of Energy, in an effort to find a solution, has put $34 million into its new GOPHURRS program, which stands for Grid Overhaul with Proactive, High-speed Undergrounding for Reliability, Resilience, and Security. The funding has been distributed across 12 projects in 11 states.

“Modernizing our nation’s power grid is essential to building a clean energy future that lowers energy costs for working Americans and strengthens our national security,” U.S. Secretary of Energy Jennifer M. Granholm says in a DOE press release.

UH and Hawaii-based Oceanit are behind one of the funded projects, entitled “Artificial Intelligence and Unmanned Aerial Vehicle Real-Time Advanced Look-Ahead Subsurface Sensor.”

The researchers are looking a developing a subsurface sensing system for underground power line installation, potentially using machine learning, electromagnetic resistivity well logging, and drone technology to predict and sense obstacles to installation.

Jiefu Chen, associate professor of electrical and computer engineering at UH, is a key collaborator on the project, focused on electromagnetic antennas installed on UAV and HDD drilling string. He's working with Yueqin Huang, assistant professor of information science technology, who leads the geophysical signal processing and Xuqing Wu, associate professor of computer information systems, responsible for integrating machine learning.

“Advanced subsurface sensing and characterization technologies are essential for the undergrounding of power lines,” says Chen in the release. “This initiative can enhance the grid's resilience against natural hazards such as wildfires and hurricanes.”

“If proven successful, our proposed look-ahead subsurface sensing system could significantly reduce the costs of horizontal directional drilling for installing underground utilities,” Chen continues. “Promoting HDD offers environmental advantages over traditional trenching methods and enhances the power grid’s resilience.”

Emission-free hydrogen research, Enron's return, and more trending Houston energy news

Aramco partners to demonstrate compact carbon capture technology for gas turbines

dream team

Integrated energy and chemicals company Aramco has signed a collaboration agreement with Carbon Clean and SAMSUNG E&A in an effort to showcase new carbon capture technology.

The technology demonstration will be used to deploy Carbon Clean’s novel CycloneCC technology to capture CO2 from natural gas turbine exhaust streams containing approximately 4 percent CO2, according to Aramco.

Carbon Clean, which U.S. headquarters are located in Houston at the Ion, boasts technology that has captured nearly two million tons of carbon dioxide at almost 50 sites around the world. Aramco’s U.S. headquarters is also in Houston.

“The potential for CycloneCC in the US and Houston area is huge,” Aniruddha Sharma, chair and CEO of Carbon Clean, previously shared with EnergyCapital. “It is optimised for low to medium scale industrial emitters and recent Rice University research on the US Gulf Coast, for example, found that it is well suited to 73 percent of Gulf Coast emitters.”

The modular CycloneCC unit has a 50 percent smaller footprint compared to conventional carbon capture processes. The CycloneCC technology is estimated to reduce the total installed cost of carbon capture systems by up to 50 percent compared to conventional systems if successful. The goal is to also maintain process efficiency even at low CO2 concentrations. CycloneCC’s performance is achieved through two process intensification technologies, rotating packed beds (RPBs) and Carbon Clean’s proprietary APBS-CDRMax solvent.

“Its compact, modular design should be easily integrated with gas turbines, delivering high performance carbon capture in an industrial setting where space is typically limited,” Sharma says in a news release.

The engineering, procurement and construction of the plant will be done by SAMSUNG E&A .The unit will be installed on the sales gas compressor turbine exhaust gas stack,which can provide performance data under real-world conditions.

“Aramco and Samsung Ventures are investors in Carbon Clean, so we’re proud to deepen our relationship through this partnership,” Sharma adds. “This first-of-a-kind deployment capturing very low concentrations of CO2 is a key milestone in scaling up and commercializing CycloneCC.”

In September, Carbon Clean also announced a deal with PETRONAS CCS Solution to collaborate and evaluate Carbon Clean’s carbon capture and storage technology with Carbon Clean's CycloneCC tech. Last year, Abu Dhabi National Oil Co. (ADNOC) selected Carbon Clean for a carbon capture project in Abu Dhabi.

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