Houston scientists discover breakthrough process for lithium-ion battery recycling

researching for the future

The Rice team's process is up to 10 times more effective than existing lithium-ion battery recycling. Photo by Gustavo Raskosky/Rice University

With the rise of electric vehicles, every ounce of lithium in lithium-ion batteries is precious. A team of scientists from Rice University has figured out a way to retrieve as much as 50 percent of the material in used battery cathodes in as little as 30 seconds.

Researchers at Rice University’s Nanomaterials Laboratory led by Department of Materials Science and NanoEngineering Chair Pulickel Ajayan released the findings a new study published in Advanced Functional Materials. Their work shows that the process overcomes a “bottleneck” in lithium-ion battery recycling technology. The researchers described a “rapid, efficient and environmentally friendly method for selective lithium recovery using microwave radiation and a readily biodegradable solvent,” according to a news release.

Past recycling methods have involved harsh acids, and alternative eco-friendly solvents like deep eutectic solvents (DESs) at times have not been as efficient and economically viable. Current recycling methods recover less than 5 percent of lithium, which is due to contamination and loss during the process.

In order to leach other metals like cobalt or nickel, both the choline chloride and the ethylene glycol have to be involved in the process, according to the researchers at Rice. The researchers submerged the battery waste material in the solvent and blasted it with microwave radiation since they knew that of the two substances only choline chloride is good at absorbing microwaves.

Microwave-assisted heating can achieve similar efficiencies like traditional oil bath heating almost 100 times faster. Using the microwave-based process, Rice found that it took 15 minutes to leach 87 percent of the lithium, which differs from the 12 hours needed to obtain the same recovery rate via oil bath heating.

“This method not only enhances the recovery rate but also minimizes environmental impact, which makes it a promising step toward deploying DES-based recycling systems at scale for selective metal recovery,” Ajayan says in the release.

Due to rise in EV production, the lithium-ion battery global market is expected to grow by over 23 percent in the next eight years, and was previously valued at over $65 billion in 2023.

“We’ve seen a colossal growth in LIB use in recent years, which inevitably raises concerns as to the availability of critical metals like lithium, cobalt and nickel that are used in the cathodes,” the study's co-author, Sohini Bhattacharyya, adds. “It’s therefore really important to recycle spent LIBs to recover these metals.”

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The DOE program allows graduate students to work on research projects that address national and international energy, environmental, and nuclear challenges. Photo via UH.edu

Houston students selected for prestigious DOE program

rising stars

Three rising stars in the energy sector who are graduate students at the University of Houston have been chosen for a prestigious U.S. Department of Energy research program.

UH doctoral candidates Caleb Broodo, Leonard Jiang, and Farzana Likhi, are among 86 students from 31 states who were selected for the Office of Science Graduate Student Research program, which provides training at Department of Energy (DOE) labs.

“This recognition is a testament to their hard work and dedication to pushing the boundaries of science, and to our commitment to fostering excellence in research and innovation,” Sarah Larsen, vice provost and dean of the UH’s graduate school, says in a news release.

The DOE program allows graduate students to work on research projects that address national and international energy, environmental, and nuclear challenges.

The program “is a unique opportunity for graduate students to complete their Ph.D. training with teams of world-class experts aiming to answer some of the most challenging problems in fundamental science,” says Harriet Kung, acting director of DOE’s Office of Science. “Gaining access to cutting-edge tools for scientific discovery at DOE national laboratories will be instrumental in preparing the next generation of scientific leaders.”

Here’s a rundown of the UH trio’s involvement in the DOE program:

Broodo, a second-year Ph.D. candidate whose research focuses on heavy ion nuclear physics, will work at Brookhaven National Laboratory in New York.
Jiang, a third-year Ph.D. candidate in materials science and engineering, will head to Argonne National Laboratory in Illinois to research electrochemistry.
Likhi, a fourth-year Ph.D. candidate in the materials science and engineering program, will conduct research on microelectronics at Oak Ridge Laboratory in Tennessee.

Junichiro Kono has assumed leadership of the Smalley-Curl Institute at Rice University. Photo via Rice.edu

Rice names new leader for prestigious nanotechnology, materials science institute

take the lead

A distinguished Rice University professor has assumed the reins of a unique institute that focuses on research within nanoscience, quantum science, and materials science.

Junichiro Kono has assumed leadership of the Smalley-Curl Institute, which houses some of the world’s most accomplished researchers across fields including advanced materials, quantum magnetism, plasmonics and photonics, biophysics and bioengineering, all aspects of nanoscience and nanotechnology, and more.

“With his great track record in fostering international research talent — with student exchange programs between the U.S., Japan, Taiwan, China, Singapore and France that have introduced hundreds of students to new cultures and ways of researching science and engineering — Jun brings a wealth of experience in building cultural and technological ties across the globe,” Ramamoorthy Ramesh, executive vice president for research, says in a news release.

Kono is the Karl F. Hasselmann Professor in Engineering, chair of the Applied Physics Graduate Program and professor of electrical and computer engineering, physics and astronomy and materials science and nanoengineering, and is considered a global leader in studies of nanomaterials and light-matter interactions. He currently leads Rice’s top 10-ranked Applied Physics Graduate Program.

Under his leadership, the program is expected to double in size over. By 2029. The Smalley-Curl Institute will also add additional postdoctoral research fellowships to the current three endowed positions.

The Smalley-Curl Institute is named for Nobel Laureates Richard Smalley and Robert Curl (‘54). Earlier in his career, Kono once worked with Smalley on the physical properties of single-wall carbon nanotubes (SWCNTs), which led to the experimental discovery of the Aharonov-Bohm effect on the band structure of SWCNTs in high magnetic fields.

“I am deeply honored and excited to lead the Smalley-Curl Institute,” Kono says in a news release. “The opportunity to build upon the incredible legacy of Richard Smalley and Robert Curl is both a privilege and a challenge, which I embrace wholeheartedly. I’m really looking forward to working with the talented researchers and students at Rice University to further advance our understanding and application of nanomaterials and quantum phenomena. Together, we can accomplish great things.”

Kono succeeds Rice professor Naomi Halas as director of the institute. Halas is the Stanley C. Moore Professor of Electrical and Computer Engineering and the founding director of the Laboratory for Nanophotonics.

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CenterPoint's resiliency plan, Chevron starts up new site, and more trending Houston energy transition news

what's trending

Editor'snote: From Chevron's new deepwater project going online to two Texas companies collaborating on energy storage, these are the top headlines that resonated with EnergyCapital readers on social media and daily newsletter this week.

CenterPoint Energy releases details of resiliency plan

To improve resiliency and reduce the risk of outages from storms or hurricanes, CenterPoint Energy announced its Greater Houston Resiliency Initiative.

The initiative will include an “accelerated timeline to execute specific actions to strengthen electric infrastructure across Houston, and more than 40 critical actions in total to strengthen the electric grid, and improve the company's customer communications and emergency coordination before the next hurricane,” according to a news release.

As part of the “Taking Action Now” section, more than 2,500 CenterPoint frontline workers and contractors will be taking a series of targeted actions to strengthen the grid and reduce the risk of outages before the next major storm that includes installing stronger and more storm-resilient poles, trimming or removal of vegetation from lines, and installing 300 automated devices, which CenterPoint says can help reenergize certain lines and lead to less without power. Continue reading.

Chevron launches production at deepwater project that aims to lower carbon intensity off offshore activity

Chevron's newest deepwater oil and natural gas production project, called the Anchor, is an all-electric facility. Photo courtesy of Chevron

Chevron's new massive deepwater oil and natural gas project in the Gulf of Mexico is officially up and running.

Chevron Corp., which recently announced its relocating its global headquarters to Houston, has officially started oil and natural gas production from its Anchor project in the U.S. Gulf of Mexico.

The semi-submersible floating production unit features a high-pressure technology that operates at up to 20,000 psi with reservoir depths reaching 34,000 feet below sea level, Chevron reports, and has a capacity of 75,000 gross barrels of oil per day and 28 million gross cubic feet of natural gas per day. Continue reading.

Two Texas companies combine to enhance hydrogen fueling, storage infrastructure

Celly offers logistics, storage, and dispensing to innovative modular refueling station services. Photo via cellyh2.com

A provider of hydrogen infrastructure solutions Celly H2 has announced its acquisition of ChemTech Energy (CNE) to continue Celly's mission of leading hydrogen fueling and storage infrastructure.

The Willis, Texas-based company offers logistics, storage, and dispensing to innovative modular refueling station services. Montgomery’s Chemtec Energy has a 25-year legacy in the oil and gas market and specializes in modular hydrogen fueling and storage infrastructure solutions.

"This acquisition marks a significant milestone for Celly as we continue to expand our portfolio in the renewable energy market," Founder and CEO of Celly Austin Terry says in a news release. Continue reading.

Houston clean energy provider raises $10.8M series A

Branch Energy aims to provide customers with clean energy at a lower cost than competitors. Photo via Getty Images

A tech-driven retail energy provider based in Houston has secured an oversubscribed series A round of funding.

Branch Energy raised a $10.8 million round led by climate-focused venture capital firm Prelude Ventures with co-investor Zero Infinity Partners, an infrastructure tech-focused firm. The fresh funding will go toward accelerating the company's battery management tech and build out the infrastructure of its field services.

A vertically integrated power provider, Branch Energy aims to provide customers with demand management software and battery storage systems to ensure long-term, stable, and clean energy at a lower cost than competitors. Continue reading.

Woodside to acquire clean ammonia project outside of Houston in $2.4B deal

OCI broke ground on the project in 2022. Photo via oci-global.com

Woodside Energy has announced its acquiring a Beaumont, Texas, clean ammonia project that's slated to deliver its first ammonia by 2025 and lower carbon ammonia by 2026.

The agreement is for Woodside to acquire 100 percent of OCI Clean Ammonia Holding and its lower carbon ammonia project in Beaumont in an all-cash deal of approximately $2.35 billion. According to Woodside CEO Meg O’Neill, the acquisition positions Woodside as an early mover in clean ammonia within the energy transition.

“This transaction positions Woodside in the growing lower carbon ammonia market," O’Neill says in a news release. "The potential applications for lower carbon ammonia are in power generation, marine fuels and as an industrial feedstock, as it displaces higher-emitting fuels. Continue reading.

New report maps Houston workforce development strategies as companies transition to cleaner energy

to-do list

The University of Houston’s Energy University latest study with UH’s Division of Energy and Innovation with stakeholders from the energy industry, academia have released findings from a collaborative white paper, titled "Workforce Development for the Future of Energy.”

UH Energy’s workforce analysis found that the greatest workforce gains occur with an “all-of-the-above” strategy to address the global shift towards low-carbon energy solutions. This would balance electrification and increased attention to renewables with liquid fuels, biomass, hydrogen, carbon capture, utilization and storage commonly known as CCUS, and carbon dioxide removal, according to a news release.

The authors of the paper believe this would support economic and employment growth, which would leverage workers from traditional energy sectors that may lose jobs during the transition.

The emerging hydrogen ecosystem is expected to create about 180,000 new jobs in the greater Houston area, which will offer an average annual income of approximately $75,000. Currently, 40 percent of Houston’s employment is tied to the energy sector.

“To sustain the Houston region’s growth, it’s important that we broaden workforce participation and opportunities,” Ramanan Krishnamoorti, vice president of energy and innovation at UH, says in a news release. “Ensuring workforce readiness for new energy jobs and making sure we include disadvantaged communities is crucial.”

Some of the key takeaways include strategies that include partnering for success, hands-on training programs, flexible education pathways, comprehensive support services, and early and ongoing outreach initiatives.

“The greater Houston area’s journey towards a low-carbon future is both a challenge and an opportunity,” Krishnamoorti continues. “The region’s ability to adapt and lead in this new era will depend on its commitment to collaboration, innovation, and inclusivity. By preparing its workforce, engaging its communities, and leveraging its industrial heritage, we can redefine our region and continue to thrive as a global energy leader.”

The study was backed by federal funding from the Department of the Treasury through the State of Texas under the Resources and Ecosystems Sustainability, Tourist Opportunities, and Revived Economies of the Gulf Coast States Act of 2012.

Houston geothermal startup selects Texas location for first energy storage facility

major milestone

Houston-based geothermal energy startup Sage Geosystems has teamed up with a utility provider for an energy storage facility in the San Antonio metro area.

The three-megawatt EarthStore facility will be on land controlled by the San Miguel Electric Cooperative, which produces electricity for customers in 47 South Texas counties. The facility will be located in the town of Christine, near the cooperative’s coal-fired power plant.

Sage says its energy storage system will be paired with solar energy to supply power for the grid operated by the Electric Reliability Council of Texas (ERCOT). The facility is set to open later this year.

“Once operational, our EarthStore facility in Christine will be the first geothermal energy storage system to store potential energy deep in the earth and supply electrons to a power grid,” Cindy Taff, CEO of Sage Geosystems, says in a news release.

The facility is being designed to store geothermal energy during six- to 10-hour periods.

“Long-duration energy storage is crucial for the ERCOT utility grid, especially with the increasing integration of intermittent wind and solar power generation,” says Craig Courter, CEO of the San Miguel Electric Cooperative.

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