The Rice team's process is up to 10 times more effective than existing lithium-ion battery recycling. Photo by Gustavo Raskosky/Rice University

With the rise of electric vehicles, every ounce of lithium in lithium-ion batteries is precious. A team of scientists from Rice University has figured out a way to retrieve as much as 50 percent of the material in used battery cathodes in as little as 30 seconds.

Researchers at Rice University’s Nanomaterials Laboratory led by Department of Materials Science and NanoEngineering Chair Pulickel Ajayan released the findings a new study published in Advanced Functional Materials. Their work shows that the process overcomes a “bottleneck” in lithium-ion battery recycling technology. The researchers described a “rapid, efficient and environmentally friendly method for selective lithium recovery using microwave radiation and a readily biodegradable solvent,” according to a news release.

Past recycling methods have involved harsh acids, and alternative eco-friendly solvents like deep eutectic solvents (DESs) at times have not been as efficient and economically viable. Current recycling methods recover less than 5 percent of lithium, which is due to contamination and loss during the process.

In order to leach other metals like cobalt or nickel, both the choline chloride and the ethylene glycol have to be involved in the process, according to the researchers at Rice. The researchers submerged the battery waste material in the solvent and blasted it with microwave radiation since they knew that of the two substances only choline chloride is good at absorbing microwaves.

Microwave-assisted heating can achieve similar efficiencies like traditional oil bath heating almost 100 times faster. Using the microwave-based process, Rice found that it took 15 minutes to leach 87 percent of the lithium, which differs from the 12 hours needed to obtain the same recovery rate via oil bath heating.

“This method not only enhances the recovery rate but also minimizes environmental impact, which makes it a promising step toward deploying DES-based recycling systems at scale for selective metal recovery,” Ajayan says in the release.

Due to rise in EV production, the lithium-ion battery global market is expected to grow by over 23 percent in the next eight years, and was previously valued at over $65 billion in 2023.

“We’ve seen a colossal growth in LIB use in recent years, which inevitably raises concerns as to the availability of critical metals like lithium, cobalt and nickel that are used in the cathodes,” the study's co-author, Sohini Bhattacharyya, adds. “It’s therefore really important to recycle spent LIBs to recover these metals.”

The DOE program allows graduate students to work on research projects that address national and international energy, environmental, and nuclear challenges. Photo via UH.edu

Houston students selected for prestigious DOE program

rising stars

Three rising stars in the energy sector who are graduate students at the University of Houston have been chosen for a prestigious U.S. Department of Energy research program.

UH doctoral candidates Caleb Broodo, Leonard Jiang, and Farzana Likhi, are among 86 students from 31 states who were selected for the Office of Science Graduate Student Research program, which provides training at Department of Energy (DOE) labs.

“This recognition is a testament to their hard work and dedication to pushing the boundaries of science, and to our commitment to fostering excellence in research and innovation,” Sarah Larsen, vice provost and dean of the UH’s graduate school, says in a news release.

The DOE program allows graduate students to work on research projects that address national and international energy, environmental, and nuclear challenges.

The program “is a unique opportunity for graduate students to complete their Ph.D. training with teams of world-class experts aiming to answer some of the most challenging problems in fundamental science,” says Harriet Kung, acting director of DOE’s Office of Science. “Gaining access to cutting-edge tools for scientific discovery at DOE national laboratories will be instrumental in preparing the next generation of scientific leaders.”

Here’s a rundown of the UH trio’s involvement in the DOE program:

  • Broodo, a second-year Ph.D. candidate whose research focuses on heavy ion nuclear physics, will work at Brookhaven National Laboratory in New York.
  • Jiang, a third-year Ph.D. candidate in materials science and engineering, will head to Argonne National Laboratory in Illinois to research electrochemistry.
  • Likhi, a fourth-year Ph.D. candidate in the materials science and engineering program, will conduct research on microelectronics at Oak Ridge Laboratory in Tennessee.
Junichiro Kono has assumed leadership of the Smalley-Curl Institute at Rice University. Photo via Rice.edu

Rice names new leader for prestigious nanotechnology, materials science institute

take the lead

A distinguished Rice University professor has assumed the reins of a unique institute that focuses on research within nanoscience, quantum science, and materials science.

Junichiro Kono has assumed leadership of the Smalley-Curl Institute, which houses some of the world’s most accomplished researchers across fields including advanced materials, quantum magnetism, plasmonics and photonics, biophysics and bioengineering, all aspects of nanoscience and nanotechnology, and more.

“With his great track record in fostering international research talent — with student exchange programs between the U.S., Japan, Taiwan, China, Singapore and France that have introduced hundreds of students to new cultures and ways of researching science and engineering — Jun brings a wealth of experience in building cultural and technological ties across the globe,” Ramamoorthy Ramesh, executive vice president for research, says in a news release.

Kono is the Karl F. Hasselmann Professor in Engineering, chair of the Applied Physics Graduate Program and professor of electrical and computer engineering, physics and astronomy and materials science and nanoengineering, and is considered a global leader in studies of nanomaterials and light-matter interactions. He currently leads Rice’s top 10-ranked Applied Physics Graduate Program.

Under his leadership, the program is expected to double in size over. By 2029. The Smalley-Curl Institute will also add additional postdoctoral research fellowships to the current three endowed positions.

The Smalley-Curl Institute is named for Nobel Laureates Richard Smalley and Robert Curl (‘54). Earlier in his career, Kono once worked with Smalley on the physical properties of single-wall carbon nanotubes (SWCNTs), which led to the experimental discovery of the Aharonov-Bohm effect on the band structure of SWCNTs in high magnetic fields.

“I am deeply honored and excited to lead the Smalley-Curl Institute,” Kono says in a news release. “The opportunity to build upon the incredible legacy of Richard Smalley and Robert Curl is both a privilege and a challenge, which I embrace wholeheartedly. I’m really looking forward to working with the talented researchers and students at Rice University to further advance our understanding and application of nanomaterials and quantum phenomena. Together, we can accomplish great things.”

Kono succeeds Rice professor Naomi Halas as director of the institute. Halas is the Stanley C. Moore Professor of Electrical and Computer Engineering and the founding director of the Laboratory for Nanophotonics.

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DOE grants $13.7M tax credit to power Houston clean hydrogen project

power move

Permascand USA Inc., a subsidiary of Swedish manufacturing company Permascand, has been awarded a $13.7 million tax credit by the U.S. Department of Energy (DOE) to expand across the country, including a new clean hydrogen manufacturing facility in Houston.

The new Houston facility will manufacture high-performance electrodes from new and recycled materials.

"We are proud to receive the support of the U.S. Department of Energy within their objective for clean energy," Permascand CEO Fredrik Herlitz said in a news release. "Our mission is to provide electrochemical solutions for the global green transition … This proposed project leverages Permascand’s experience in advanced technologies and machinery and will employ a highly skilled workforce to support DOE’s initiative in lowering the levelized cost of hydrogen.”

The funding comes from the DOE’s Qualifying Advanced Energy Project Credit program, which focuses on clean energy manufacturing, recycling, industrial decarbonization and critical materials projects.

The Permascand proposal was one of 140 projects selected by the DOE with over 800 concept papers submitted last summer. The funding is part of $6 billion in tax credits in the second round of the Qualifying Advanced Energy Project Credit program that was deployed in January.

So far credits have been granted to approximately 250 projects across more than 40 states, with project investments over $44 billion dollars, according to the Department of Treasury. Read more here.

Houston researchers reach 'surprising' revelation in materials recycling efforts

keep it clean

Researchers at Rice University have published a study in the journal Carbon that demonstrates how carbon nanotube (CNT) fibers can be fully recycled without any loss in their structure or properties.

The discovery shows that CNT fibers could be used as a sustainable alternative to traditional materials like metals, polymers and the larger, harder-to-recycle carbon fibers, which the team hopes can pave the way for more sustainable and efficient recycling efforts.

“Recycling has long been a challenge in the materials industry — metals recycling is often inefficient and energy intensive, polymers tend to lose their properties after reprocessing and carbon fibers cannot be recycled at all, only downcycled by chopping them up into short pieces,” corresponding author Matteo Pasquali, director of Rice’s Carbon Hub and the A.J. Hartsook Professor of Chemical and Biomolecular Engineering, Materials Science and NanoEngineering and Chemistry, explained in a news release. “As CNT fibers are being scaled up, we asked whether and how these new materials could be recycled in the future .... We expected that recycling would be difficult and would lead to significant loss of properties. Surprisingly, we found that carbon nanotube fibers far exceed the recyclability potential of existing engineered materials, offering a solution to a major environmental issue.”

Rice researchers used a solution-spun CNT fiber that was created by dissolving fiber-grade commercial CNTs in chlorosulfonic acid, according to Rice. Mixing the two fibers led to complete redissolution and no sign of separation of the two source materials into different liquid phases. This redissolved material was spun into a mixed-source recycled fiber that retained the same structure and alignment, which was unprecedented.

Pasquali explained in a video release that the new material has properties that overlap with and could be a replacement for carbon fibers, kevlar, steel, copper and aluminum.

“This preservation of quality means CNT fibers can be used and reused in demanding applications without compromising performance, thus extending their lifecycle and reducing the need for new raw materials,” co-first author Ivan R. Siqueira, a recent doctoral graduate in Rice’s Department of Chemical and Biomolecular Engineering, said in a news release.

Other co-authors of the paper are Rice graduate alumni Oliver Dewey, now of DexMat; Steven Williams; Cedric Ginestra, now of LyondellBasell; Yingru Song, now a postdoctoral fellow at Purdue University; Rice undergraduate alumnus Juan De La Garza, now of Axiom Space; and Geoff Wehmeyer, assistant professor of mechanical engineering.

The research is part of the broader program of the Rice-led Carbon Hub, an initiative to develop a zero-emissions future. The work was also supported by the Department of Energy’s Advanced Research Project Agency, the Air Force Office of Scientific Research and a number of other organizations.

Pasquali recently led another team of Rice researchers to land a $4.1 million grant to optimize CNT synthesis. The funds came from Rice’s Carbon Hub and The Kavli Foundation. Read more here.

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