Houston-based Citroniq Chemicals has secured its series A funding. Photo via Getty Images

A fresh $12 million round of funding will enable Houston-based Citroniq Chemicals to propel planning, design, and construction of its first decarbonization plant.

An unidentified multinational energy technology company led the series A round, with participation from Houston-based Lummus Technology Ventures and cooperation from the State of Nebraska. The Citroniq plant, which will produce green polypropylene, will be located in Nebraska.

“Lummus’ latest investment in Citroniq builds on this progress and strengthens our partnership, working together to lower carbon emissions in the plastics industry,” Leon de Bruyn, president and CEO of Lummus Technology, says in a news release.

Citroniq is putting together a decarbonization platform designed to annually capture 2 million metric tons of greenhouse gas emissions at each plant. The company plans to invest more than $5 billion into its green polypropylene plants. Polypropylene is a thermoplastic resin commonly used for injection molding.

The series A round “is just the first step in our journey towards building multiple biomanufacturing hubs, boosting the Nebraska bioeconomy by converting local ethanol into valuable bioplastics,” says Kelly Knopp, co-founder and CEO of Citroniq.

Citroniq’s platform for the chemical and plastics industries uses technology and U.S.-produced ethanol to enable low-cost carbon capture. Citroniq’s process permanently sequesters carbon into a useful plastic pellet.

Lummus Technology licenses process technologies for clean fuels, renewables, petrochemicals, polymers, gas processing and supply lifecycle services, catalysts, proprietary equipment, and digital transformation.

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This article originally ran on InnovationMap.

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Mitsubishi, ExxonMobil announce low-carbon ammonia production partnership in Baytown

dream team

Spring-based ExxonMobil has teamed up with Japan’s Mitsubishi to potentially produce low-carbon ammonia and nearly carbon-free hydrogen at ExxonMobil’s facility in Baytown.

ExxonMobil and Mitubishi are still working out details of the arrangement, such as equity participation in the project and use of the low-carbon ammonia.

“We look forward to furthering our leadership position, alongside Mitsubishi Corporation, to advance low-carbon hydrogen and ammonia globally, helping the world achieve a lower emission future,” Dan Ammann, president of ExxonMobil Low Carbon Solutions, says in a news release.

The ammonia would be shipped to Japan for power generation, process heating, and other industrial purposes. In conjunction with this project, Mitsubishi would convert part of a liquified petroleum gas (LPG) terminal into an ammonia terminal. The Japanese conglomerate plans to partner with Japanese petroleum company Idemitsu Kosan for ammonia purchases and a joint equity stake in the Baytown project.

The Baytown project is expected to generate as much as one billion cubic square feet of low-carbon hydrogen per day and more than one million tons of low-carbon ammonia per year.

A financial decision on the project is set for 2025, with the project coming online in 2029.

“We are excited to be closely collaborating with ExxonMobil to develop low-carbon hydrogen and ammonia supply chains that will bridge the United States and Japan,” says Masaru Saito, CEO of Mitsubishi’s Environmental Energy Group. “Together, we will lead this joint initiative to assist in the acceleration of the hard-to-abate sectors’ transition to clean energy.”

9 carbontech startups named to Greentown Labs accelerator program

new cohort

A carbon innovation initiative in collaboration with Greentown Houston has named its new cohort.

The Carbon to Value Initiative (C2V Initiative) — a collaboration between NYU Tandon School of Engineering's Urban Future Lab (UFL), Greentown Labs, and Fraunhofer USA — has named nine startup participants for the fourth year of its carbontech accelerator program.

"Once again, the C2V Initiative has been able to select some of the most promising carbontech startups through a very competitive process with a 7 percent acceptance rate," Frederic Clerc, director of the C2V Initiative and interim managing director of UFL, says in a news release. "The diversity of this cohort, in its technologies, products, geographies, and stages, makes it an amazing snapshot of the rapidly evolving carbontech innovation landscape."

The cohort was selected from over a hundred applications from nearly 30 countries. In the six-month program, the nine companies gain access to the C2V Initiative's Carbontech Leadership Council, an invitation-only group of corporate, nonprofit, and government leaders who provide commercialization opportunities and identify avenues for technology validation, testing, and demonstration.

The year four cohort, according to the release, includes:

  • Ardent, from New Castle, Delaware, is a process technology company that is developing membrane-based solutions for point-source carbon capture and other chemical separations.
  • CarbonBlue, from Haifa, Israel, develops a chemical process that mineralizes and extracts CO2 from water, which then reabsorbs more atmospheric CO2.
  • MacroCycle, from Somerville, Massachusetts, develops a chemical recycling process to turn polyethylene terephthalate (PET) and polyester-fiber waste into "virgin-grade" plastics.
  • Maple Materials, from Richmond, California,develops an electrolysis process to convert CO2 into graphite and oxygen.
  • Oxylus Energy, from New Haven, Connecticut, develops a direct electrochemical process to convert CO2 into fuels and chemical feedstocks, such as methanol.
  • Phlair, from Munich, Germany, develops a renewable-energy-powered Direct Air Capture (DAC) system using an electrochemical process for acid and base generation.
  • Secant Fuel, from Montreal, Quebec, Canada, develops a one-step electrocatalytic process that converts flue gas into syngas.
  • RenewCO2, from Somerset, New Jersey, is developing an electrochemical process to convert CO2 into fuels and chemicals, such as sustainable aviation fuel (SAF) or propylene glycol.
  • Seabound, from London, England, builds carbon-capture equipment for new and existing ships.

"The depth and breadth of carbontech innovations represented in this applicant pool speaks volumes to this growing and dynamic industry around the world," adds Kevin Dutt, Interim CEO of Greentown Labs. "We're eager to support these nine impressive companies as they progress through this program and look forward to seeing how they engage with the CLC now and into the future."

The C2V Initiative will host a public Year 4 kickoff event on Sept. 19 at Greentown Houston and via livestream.

Hundreds of homes near Houston still under evacuation orders as pipeline fire burns for second day

news update

A pipeline fire that erupted in a suburban Houston neighborhood burned throughout a second day and into the night Tuesday with still no definitive word on when the blaze would finally go out, when nearby residents may be able to return home or why a car drove through a fence and hit a valve before the destructive explosion.

Although the fire was getting smaller, the disruptions caused by the Monday morning explosion in a grassy corridor between a Walmart and a residential neighborhood left some locals increasingly weary. On Tuesday, people could be seen returning to their homes to get clothes and other items before quickly leaving again.

“We literally walked out with the clothes on our backs, the pets, and just left the neighborhood with no idea where we were going,” Kristina Reff said. “That was frustrating.”

Over 36 hours after the blast — which shot towering flames like a blowtorch above the suburbs of Deer Park and La Porte — authorities have provided few details about the circumstances leading up to the explosion.

Investigators said it happened after the driver of a sport utility vehicle went through a fence near the Walmart and struck an above-ground valve. As of Tuesday evening, authorities had not still not identified the driver or said what happened to them.

Deer Park officials have said police and FBI agents found no preliminary evidence to suggest the explosion of the pipeline, which carried natural gas liquids, was a coordinated or terrorist attack. In a statement Monday night, the city said it “appears to be an isolated incident” but officials have not provided details on how they came to that conclusion.

The car was incinerated by the explosion, which scorched the ground across a wide radius, severed power transmission lines, melted playground equipment and ignited some homes.

The valve, which appears to have been protected by a chain-link fence topped with barbed wire, is located within a long grassy field where high-voltage power lines run. Several pipelines run underground.

Authorities evacuated nearly 1,000 homes at one point and ordered people in nearby schools to shelter in place. By Tuesday afternoon that number was down to just over 400.

“The fire is still burning, but the good news is that the pressure within the pipeline is continuously dropping, which means we are getting closer to the fire going out,” Harris County Judge Lina Hidalgo said in a statement.

Operators shut off the flow after the explosion, but Hidalgo has said that 20 miles (32 kilometers) of pipeline stretched between the two closed valves and the chemicals inside had to burn off before the fire would stop.

Robert Hall, a senior advisor at the nonprofit Pipeline Safety Trust, said it’s not surprising that it’s taken more than a day for the material to stop burning.

“You’re talking about 20-inch pipelines and miles between valves, so it takes a long time to burn down,” Hall said.

On Tuesday, the Texas Railroad Commission that regulates the state’s oil and gas industry said its inspectors only will enter the site after it is deemed safe by emergency authorities.

Houston is the nation’s petrochemical heartland and is home to a cluster of refineries and plants and thousands of miles of pipelines. Explosions and fires are a familiar sight, and some have been deadly, raising recurring questions about industry efforts to protect the public and the environment.

Hall, who previously oversaw pipeline and hazardous materials investigations for the National Transportation Safety Board, said there are few regulations that govern the location of pipelines near homes and businesses.

“That becomes a very local issue, community by community,” Hall said, adding that some jurisdictions require bollards — sturdy pipes filled with concrete — to prevent vehicles from crashing into sensitive infrastructure.

Hidalgo said Tuesday that Energy Transfer, the Dallas-based owner of the pipeline, has said it was working to isolate parts of the pipeline closest to the fire by clamping it on each side.

Energy Transfer did not immediately respond to a question about what safety precautions were in place near the valve.

Hall said regulations from 2022 aimed at reducing deaths and environmental damage from ruptures were geared toward gas lines, not those carrying liquids, and would not have applied to this pipeline. He added that many new safety regulations that have been put in place do not apply retroactively to pre-existing pipelines.

Both Energy Transfer and Harris County Pollution Control were conducting air monitoring in the area and have found no health issues, according to Deer Park officials.

Since leaving home, Reff and her family have been staying in a hotel room paid for by Energy Transfer. But they were eager to return.

“It would be nice to be in our own beds,” she said.